trans-[FeH(acetonitrile)(dppe)2][BF₄]

Base Information

Chemical Name:trans-[FeH(acetonitrile)(dppe)2][BF₄]
CAS No.:252659-25-9
Molecular Formula:BF₄*C₅₄H₅₂FeNP₄
Molecular Weight:981.56
Hs Code.:

trans-[FeH(acetonitrile)(dppe)2][BF<sub>4</sub>]

Synonyms:

Suppliers and Price of trans-[FeH(acetonitrile)(dppe)2][BF₄]

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of trans-[FeH(acetonitrile)(dppe)2][BF₄]

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of trans-[FeH(acetonitrile)(dppe)2][BF₄]

There total 3 articles about trans-[FeH(acetonitrile)(dppe)2][BF₄] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 13755-29-8
sodium tetrafluoroborate

: 252659-24-8
trans-[FeH(acetonitrile)(dppe)2]Cl

: 75-05-8,26809-02-9
acetonitrile

: 252659-25-9
trans-[FeH(acetonitrile)(dppe)2][BF₄]

Guidance literature:: In acetonitrile; byproducts: NaCl; Ar-atmosphere; slight excess of NaBF4, stirring for 14 h; solvent removal (vac.), extn. into CH2Cl2, solvent removal (vac.), recrystn. (CH2Cl2/hexane); elem. anal.;
DOI:10.1016/S0022-328X(99)00392-7

Reference yield: 72.0%

: trans-[iron(II) hydride (η2-dihydrogen)bis[1,2-bis(diphenylphosphanyl)ethane]] tetrafluoroborate

: 75-05-8,26809-02-9
acetonitrile

: 252659-25-9
trans-[FeH(acetonitrile)(dppe)2][BF₄]

Guidance literature:: In acetonitrile; byproducts: H2; (H2); standard Schlenk technique; soln. of Fe complex in CH3CN was stirred at room temp. for 12 h; concd.; Et2O added; septd.; dried (vac.); crystd. at room temp. by diffusion of Et2O into CH2Cl2 soln. containing few drops of nitrile over several d;

Reference yield:

: trans-[(1,2-bis(diphenylphosphino)ethane)2Fe(η2-H2)(CH3CN)][BF4]2

: 252659-25-9
trans-[FeH(acetonitrile)(dppe)2][BF₄]

Guidance literature:: With triethylamine or pyridine or piperidine; In chloroform-d1; byproducts: triethylammonium or pyrdininium or piperidinium; (H2); standard Schlenk technique; Fe complex was reacted with triethylamine or pyridine or piperidine;