[(η(6)-C6Me6)Ru(2,6-xylyl isocyanide)(P(2-O-6-MeOC6H3)Ph2-O,P)]PF6

Base Information

• Chemical Name: [(η(6)-C6Me6)Ru(2,6-xylyl isocyanide)(P(2-O-6-MeOC6H3)Ph2-O,P)]PF6
• CAS No.: 215517-12-7
• Molecular Formula: C₄₀H₄₃NO₂PRu*F₆P
• Molecular Weight: 846.795
• Mol file: 215517-12-7.mol

Synonyms:

Chemical Property of [(η(6)-C6Me6)Ru(2,6-xylyl isocyanide)(P(2-O-6-MeOC6H3)Ph2-O,P)]PF6

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of [(η(6)-C6Me6)Ru(2,6-xylyl isocyanide)(P(2-O-6-MeOC6H3)Ph2-O,P)]PF6

There total 1 articles about [(η(6)-C6Me6)Ru(2,6-xylyl isocyanide)(P(2-O-6-MeOC6H3)Ph2-O,P)]PF6 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

ammonium hexafluorophosphate + (η(6)-hexamethylbenzene)RuCl[PPh2(2-O-C6H3-6-OMe)] (176207-48-0) + 2,6-dimethylphenyl isonitrile (119072-54-7,2769-71-3) → [(η(6)-C6Me6)Ru(2,6-xylyl isocyanide)(P(2-O-6-MeOC6H3)Ph2-O,P)]PF6 (215517-12-7)

Guidance literature:

In dichloromethane; acetone; N2-atmosphere; addn. of excess NH4PF6 (in Me2CO) to mixt. of Ru-complex with 2 equiv. of isocyanide (in CH2Cl2), stirring (room temp., 2 h); solvent removal (reduced pressure), extn. into CH2Cl2, filtration, solvent removal, crystn. (CH2Cl2/Et2O); elem. anal.;

DOI:10.1016/S0022-328X(98)00771-2

upstream raw materials:

(η(6)-hexamethylbenzene)RuCl[PPh2(2-O-C6H3-6-OMe)]

2,6-dimethylphenyl isonitrile