Palladium, (benzeneselenolato)chloro-

Base Information

• Chemical Name: Palladium, (benzeneselenolato)chloro-
• CAS No.: 127441-30-9
• Molecular Formula: C6H5ClPdSe
• Molecular Weight: 297.939
• Mol file: 127441-30-9.mol

Synonyms:

Chemical Property of Palladium, (benzeneselenolato)chloro-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Palladium, (benzeneselenolato)chloro-

There total 4 articles about Palladium, (benzeneselenolato)chloro- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

sodium tetrachloropalladate(II) + diphenyl diselenide (1666-13-3) → phenylselenol palladium(II) Cl (127441-30-9)

Guidance literature:

With sodium tetrahydroborate; In ethanol; water; react. under dry N2, reduction of Ar2Se2 by NaBH4, addn. of the Pd complex, molar ratio of Na2PdCl4 : Ar2Se2 = 1:1, stirring for 6 h at room temp., pptn.; separation by centrifugation, washing with water, alcohol and ether, drying in vac., elem. anal.;

DOI:10.1016/S0020-1693(00)80811-7

Reference yield: 58.0%

Pb(SePh)2 + [Pd2Cl2(μ-Cl)2(tri(methylallyl)arsine)2] (654055-90-0) → [PdCl(SeC6H5)] (127441-30-9)

Guidance literature:

In dichloromethane; (N2); addn. of Pb(SePh)2 to stirred soln. of Pd2Cl2(μ-Cl)2(As(CH2CMeCH2)3)2 in CH2Cl2; stirring for 3 h; filtration, evapn. of solvent in vac., elem. anal.;

DOI:10.1039/b303990k

Reference yield:

{PdCl2(Se2(C6H5)2)}2 (127416-20-0) → phenylselenol palladium(II) Cl (127441-30-9)

Guidance literature:

In methanol; ethanol; refluxing in methanol/ethanol; successive washings with methanol/ethanol and CHCl3;

DOI:10.1016/S0020-1693(00)80811-7

upstream raw materials:

[Pd2Cl2(μ-Cl)2(tri(methylallyl)arsine)2]

[PdCl(μ-Cl)(tri(allyl)arsine)]2

{PdCl₂(Se₂(C₆H₅)2)}2

diphenyl diselenide

Downstream raw materials:

{PdCl(SeC₆H₅)((C₆H₅)2PCH₂)2}

trans-{PdCl(SePh)(PPh₃)2}