6-((4-(3-(3-methoxyphenyl)-3,3-diphenylprop-1-yn-1-yl)phenyl)ethynyl)-13-(oct-1-yn-1-yl)-5,7,12,14-tetrahydro-5,14:7,12-bis([1,2]benzeno)pentacene

Base Information

Chemical Name:6-((4-(3-(3-methoxyphenyl)-3,3-diphenylprop-1-yn-1-yl)phenyl)ethynyl)-13-(oct-1-yn-1-yl)-5,7,12,14-tetrahydro-5,14:7,12-bis([1,2]benzeno)pentacene
CAS No.:1436388-22-5
Molecular Formula:C₇₂H₅₄O
Molecular Weight:935.22
Hs Code.:

6-((4-(3-(3-methoxyphenyl)-3,3-diphenylprop-1-yn-1-yl)phenyl)ethynyl)-13-(oct-1-yn-1-yl)-5,7,12,14-tetrahydro-5,14:7,12-bis([1,2]benzeno)pentacene

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Chemical Property of 6-((4-(3-(3-methoxyphenyl)-3,3-diphenylprop-1-yn-1-yl)phenyl)ethynyl)-13-(oct-1-yn-1-yl)-5,7,12,14-tetrahydro-5,14:7,12-bis([1,2]benzeno)pentacene

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Technology Process of 6-((4-(3-(3-methoxyphenyl)-3,3-diphenylprop-1-yn-1-yl)phenyl)ethynyl)-13-(oct-1-yn-1-yl)-5,7,12,14-tetrahydro-5,14:7,12-bis([1,2]benzeno)pentacene

There total 4 articles about 6-((4-(3-(3-methoxyphenyl)-3,3-diphenylprop-1-yn-1-yl)phenyl)ethynyl)-13-(oct-1-yn-1-yl)-5,7,12,14-tetrahydro-5,14:7,12-bis([1,2]benzeno)pentacene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 27.0%

: 1436388-19-0
(3-(4-iodophenyl)-1-(3-methoxyphenyl)prop-2-yne-1,1-diyl)dibenzene

: 1436388-21-4
6-ethynyl-13-(oct-1-yn-1-yl)-5,7,12,14-tetrahydro-5,14:7,12-bis([1,2]benzeno)pentacene

: 1436388-22-5
6-((4-(3-(3-methoxyphenyl)-3,3-diphenylprop-1-yn-1-yl)phenyl)ethynyl)-13-(oct-1-yn-1-yl)-5,7,12,14-tetrahydro-5,14:7,12-bis([1,2]benzeno)pentacene

Guidance literature:: With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; diisopropylamine; In tetrahydrofuran; for 13.5h; Inert atmosphere;
DOI:10.1021/jo4004053

Reference yield:

: 6932-41-8
5,7,12,14-tetrahydro-5,14<1',2'>:7,12<1'',2''>-dibenzenopentacene-6,13-dione

: 1436388-22-5
6-((4-(3-(3-methoxyphenyl)-3,3-diphenylprop-1-yn-1-yl)phenyl)ethynyl)-13-(oct-1-yn-1-yl)-5,7,12,14-tetrahydro-5,14:7,12-bis([1,2]benzeno)pentacene

Guidance literature:: Multi-step reaction with 3 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / -78 °C / Inert atmosphere

1.2: -78 °C / Inert atmosphere

1.3: 20 °C / Inert atmosphere

2.1: potassium hydroxide / water; methanol / 20 °C

3.1: diisopropylamine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide / tetrahydrofuran / 13.5 h / Inert atmosphere

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; n-butyllithium; diisopropylamine; potassium hydroxide; In tetrahydrofuran; methanol; hexane; water; 3.1: |Sonogashira Cross-Coupling;
DOI:10.1021/jo4004053

Reference yield:

: 629-05-0
n-octyne

: 1436388-22-5
6-((4-(3-(3-methoxyphenyl)-3,3-diphenylprop-1-yn-1-yl)phenyl)ethynyl)-13-(oct-1-yn-1-yl)-5,7,12,14-tetrahydro-5,14:7,12-bis([1,2]benzeno)pentacene

Guidance literature:: Multi-step reaction with 3 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / -78 °C / Inert atmosphere

1.2: -78 °C / Inert atmosphere

1.3: 20 °C / Inert atmosphere

2.1: potassium hydroxide / water; methanol / 20 °C

3.1: diisopropylamine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide / tetrahydrofuran / 13.5 h / Inert atmosphere

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; n-butyllithium; diisopropylamine; potassium hydroxide; In tetrahydrofuran; methanol; hexane; water; 3.1: |Sonogashira Cross-Coupling;
DOI:10.1021/jo4004053