Technology Process of 4,4'-(1-phenylethane-1,1-diyl)bis((fluoromethoxy)benzene)
There total 3 articles about 4,4'-(1-phenylethane-1,1-diyl)bis((fluoromethoxy)benzene) which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
tris(bipyridine)ruthenium(II) dichloride hexahydrate; Selectfluor; sodium hydroxide;
In
water; acetonitrile;
for 1h;
Inert atmosphere;
Irradiation;
DOI:10.1021/ja412083f
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: potassium carbonate / N,N-dimethyl-formamide / 0.5 h / 20 °C / Ionic liquid; Inert atmosphere
1.2: 18 h / 20 °C / Inert atmosphere
2.1: lithium hydroxide monohydrate / methanol / Reflux; Inert atmosphere
2.2: pH > 12 / Inert atmosphere
3.1: Selectfluor; sodium hydroxide; tris(bipyridine)ruthenium(II) dichloride hexahydrate / water; acetonitrile / 1 h / Inert atmosphere; Irradiation
With
tris(bipyridine)ruthenium(II) dichloride hexahydrate; lithium hydroxide monohydrate; potassium carbonate; Selectfluor; sodium hydroxide;
In
methanol; water; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1021/ja412083f
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: lithium hydroxide monohydrate / methanol / Reflux; Inert atmosphere
1.2: pH > 12 / Inert atmosphere
2.1: Selectfluor; sodium hydroxide; tris(bipyridine)ruthenium(II) dichloride hexahydrate / water; acetonitrile / 1 h / Inert atmosphere; Irradiation
With
tris(bipyridine)ruthenium(II) dichloride hexahydrate; lithium hydroxide monohydrate; Selectfluor; sodium hydroxide;
In
methanol; water; acetonitrile;
DOI:10.1021/ja412083f
