pseudo-meta-bromo-<2.2>paracyclophane-4-carboxylic acid

Base Information

• Chemical Name: pseudo-meta-bromo-<2.2>paracyclophane-4-carboxylic acid
• CAS No.: 56439-07-7
• Molecular Formula: C₁₇H₁₅BrO₂
• Molecular Weight: 331.209
• Mol file: 56439-07-7.mol

Synonyms:

Chemical Property of pseudo-meta-bromo-<2.2>paracyclophane-4-carboxylic acid

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of pseudo-meta-bromo-<2.2>paracyclophane-4-carboxylic acid

There total 3 articles about pseudo-meta-bromo-<2.2>paracyclophane-4-carboxylic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

methyl pseudo-meta-bromo-<2.2>paracyclophane-4-carboxylate (1228600-68-7) → pseudo-meta-bromo-<2.2>paracyclophane-4-carboxylic acid (56439-07-7,65635-79-2,309276-71-9,770737-09-2,1228600-69-8)

Guidance literature:

With potassium hydroxide; In water;

DOI:10.1016/S0040-4020(00)00644-X

Reference yield: 78.0%

(S)-4-bromo-13-(4-isopropyl-2-oxazolin-2-yl)[2.2]paracyclophane → pseudo-meta-bromo-<2.2>paracyclophane-4-carboxylic acid (56439-07-7,65635-79-2,309276-71-9,770737-09-2,1228600-69-8)

Guidance literature:

(S)-4-bromo-13-(4-isopropyl-2-oxazolin-2-yl)[2.2]paracyclophane; With methyl iodide; In dimethyl sulfoxide; at 20 ℃;

With potassium hydroxide; In water; Heating;

DOI:10.1016/j.tetasy.2004.06.026

Reference yield:

→ pseudo-meta-bromo-<2.2>paracyclophane-4-carboxylic acid (56439-07-7,65635-79-2,309276-71-9,770737-09-2,1228600-69-8)

Guidance literature:

43, Verseifung;

DOI:10.1021/ja00846a038

upstream raw materials:

methyl pseudo-meta-bromo-<2.2>paracyclophane-4-carboxylate

Downstream raw materials:

(4Sp,13Rp)-4-bromo-13-(4,4-dimethyl-2-oxazolin-2-yl)[2.2]paracyclophane

4-phenylthio-13-(4,4-dimethyloxazolin-2-yl)[2.2]paracyclophane