[C₆F₅Xe]⁽¹⁺⁾*[B(CN)4]^(1-)=[C₆F₅Xe][B(CN)4]

Base Information

• Chemical Name: [C₆F₅Xe]⁽¹⁺⁾*[B(CN)4]^(1-)=[C₆F₅Xe][B(CN)4]
• CAS No.: 1019339-58-2
• Molecular Formula: C₄BN₄*C₆F₅Xe
• Molecular Weight: 413.23
• Mol file: 1019339-58-2.mol

Synonyms:

Chemical Property of [C₆F₅Xe]⁽¹⁺⁾*[B(CN)4]^(1-)=[C₆F₅Xe][B(CN)4]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [C₆F₅Xe]⁽¹⁺⁾*[B(CN)4]^(1-)=[C₆F₅Xe][B(CN)4]

There total 2 articles about [C₆F₅Xe]⁽¹⁺⁾*[B(CN)4]^(1-)=[C₆F₅Xe][B(CN)4] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

pentafluorophenylxenonium(II) tetrafluoroborate (215500-01-9) + tetracyanoborate anion (261356-47-2) → [C6F5Xe](1+)*[B(CN)4](1-)=[C6F5Xe][B(CN)4] (1019339-58-2)

Guidance literature:

In acetonitrile; soln. of B salt in MeCN and soln. of Xe compd. in MeCN were combined at room temp.; cooled to -40°C; centrifuged at -40°C; mother liquor septd.; residue washed (cold MeCN); solvent removed (vac., room temp.); pumped (vac., 20°C, 12 h);

DOI:10.1021/ic702259c

Reference yield: 99.0%

potassium tetracyanoborate + pentafluorophenylxenonium(II) tetrafluoroborate (215500-01-9) → [C6F5Xe](1+)*[B(CN)4](1-)=[C6F5Xe][B(CN)4] (1019339-58-2)

Guidance literature:

In acetonitrile; byproducts: KBF4; mixing acetonitrile solns. of xenon compd. and potassium salt at 20°C, stirring for 15 min; cooling to -40°C, centrifugation, washing ppt. with CH3CN, combining CH3CN solns., evapn., drying in vac. for hs at 20°C, NMR;

DOI:10.1021/ic7010138

upstream raw materials:

pentafluorophenylxenonium(II) tetrafluoroborate

tetracyanoborate anion