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dicarbonyl-η5-[1-(5,5-dimethylhex-3-ynyl)-3-phenylcyclopentadienyl]rhodium(I)

Base Information
  • Chemical Name:dicarbonyl-η5-[1-(5,5-dimethylhex-3-ynyl)-3-phenylcyclopentadienyl]rhodium(I)
  • CAS No.:953395-70-5
  • Molecular Formula:C21H21O2Rh
  • Molecular Weight:408.302
  • Hs Code.:
dicarbonyl-η5-[1-(5,5-dimethylhex-3-ynyl)-3-phenylcyclopentadienyl]rhodium(I)

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Chemical Property of dicarbonyl-η5-[1-(5,5-dimethylhex-3-ynyl)-3-phenylcyclopentadienyl]rhodium(I)
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Technology Process of dicarbonyl-η5-[1-(5,5-dimethylhex-3-ynyl)-3-phenylcyclopentadienyl]rhodium(I)

There total 1 articles about dicarbonyl-η5-[1-(5,5-dimethylhex-3-ynyl)-3-phenylcyclopentadienyl]rhodium(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:
Guidance literature:
With n-butyllithium; In tetrahydrofuran; hexane; under Ar; n-BuLi in hexane was added to soln. of cyclopentadiene ligand in THF at -78°C, after warming up to room temp. the soln. was added to soln. of Rh complex in THF and stirred for 24 h; solvent was removed under vac., residue was chromd. (flash column, silica gel, pentane as eluent), solvent was evapd.; NMR, IR, MAS;
DOI:10.1016/j.jorganchem.2007.06.053
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