(S)-4-(1,3-Benzodioxol-5-ylmethyl)-3-[(Z)-1,3-benzodioxol-5-ylmethylene]dihydro-2(3H)-furanone

Base Information

• Chemical Name: (S)-4-(1,3-Benzodioxol-5-ylmethyl)-3-[(Z)-1,3-benzodioxol-5-ylmethylene]dihydro-2(3H)-furanone
• CAS No.: 15914-41-7
• Molecular Formula: C₂₀H₁₆O₆
• Molecular Weight: 352.343
• Mol file: 15914-41-7.mol

Synonyms:2(3H)-Furanone,4-(1,3-benzodioxol-5-ylmethyl)-3-(1,3-benzodioxol-5-ylmethylene)dihydro-,[S-(Z)]-; 2(3H)-Furanone, dihydro-4-piperonyl-3-piperonylidene-, (Z)- (8CI);Gadain

Chemical Property of (S)-4-(1,3-Benzodioxol-5-ylmethyl)-3-[(Z)-1,3-benzodioxol-5-ylmethylene]dihydro-2(3H)-furanone

Chemical Property:

• Boiling Point: 573.5±39.0 °C(Predicted)
• PSA: 63.22000
• Density: 1.439±0.06 g/cm3(Predicted)
• LogP: 2.94310

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (S)-4-(1,3-Benzodioxol-5-ylmethyl)-3-[(Z)-1,3-benzodioxol-5-ylmethylene]dihydro-2(3H)-furanone

There total 5 articles about (S)-4-(1,3-Benzodioxol-5-ylmethyl)-3-[(Z)-1,3-benzodioxol-5-ylmethylene]dihydro-2(3H)-furanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(S)-2-Benzo[1,3]dioxol-5-ylmethyl-3-[1-benzo[1,3]dioxol-5-yl-meth-(Z)-ylidene]-butane-1,4-diol (94480-05-4) → gadain (15914-41-7)

Guidance literature:

With manganese(IV) oxide; In acetone; for 20h;

DOI:10.1016/S0031-9422(00)80544-0

Reference yield:

3-(1',3'-benzodioxol-5'-ylmethylene)-4-(3'',4''-dimethoxybenzyl)dihydrofuran-2(5H)-one (50816-74-5) → gadain (15914-41-7)

Guidance literature:

Multi-step reaction with 3 steps

1: 14 mg / BBr₃ / CH₂Cl₂ / 12 h / Ambient temperature

2: 5 mg / K₂CO₃ / acetone / Heating

3: 2 mg / acetone / 12 h / Irradiation

With boron tribromide; potassium carbonate; In dichloromethane; acetone;

DOI:10.1016/S0031-9422(00)80544-0

Reference yield:

(S)-3-[1-Benzo[1,3]dioxol-5-yl-meth-(E)-ylidene]-4-(3,4-dihydroxy-benzyl)-dihydro-furan-2-one (94285-08-2) → gadain (15914-41-7)

Guidance literature:

Multi-step reaction with 2 steps

1: 5 mg / K₂CO₃ / acetone / Heating

2: 2 mg / acetone / 12 h / Irradiation

With potassium carbonate; In acetone;

DOI:10.1016/S0031-9422(00)80544-0

upstream raw materials:

hibalactone

(S)-2-Benzo[1,3]dioxol-5-ylmethyl-3-[1-benzo[1,3]dioxol-5-yl-meth-(Z)-ylidene]-butane-1,4-diol

3-(1',3'-benzodioxol-5'-ylmethylene)-4-(3'',4''-dimethoxybenzyl)dihydrofuran-2(5H)-one

(S)-3-[1-Benzo[1,3]dioxol-5-yl-meth-(E)-ylidene]-4-(3,4-dihydroxy-benzyl)-dihydro-furan-2-one