[Nb(HC(C(Me)NC₆H₃-2,6-(iPr)2)2)(NBu-t)Cl₂]

Base Information

• Chemical Name: [Nb(HC(C(Me)NC₆H₃-2,6-(iPr)2)2)(NBu-t)Cl₂]
• CAS No.: 1233373-56-2
• Molecular Formula: C₃₃H₅₀Cl₂N₃Nb
• Molecular Weight: 652.592

Synonyms:

Chemical Property of [Nb(HC(C(Me)NC₆H₃-2,6-(iPr)2)2)(NBu-t)Cl₂]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Nb(HC(C(Me)NC₆H₃-2,6-(iPr)2)2)(NBu-t)Cl₂]

There total 2 articles about [Nb(HC(C(Me)NC₆H₃-2,6-(iPr)2)2)(NBu-t)Cl₂] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

Li[(2,6-iPr2(C6H3))NC(Me)CH(Me)CN(2,6-iPr2(C6H3))]*Et2O + [Nb(NBu-t)Cl3(dme)] → [Nb(HC(C(Me)NC6H3-2,6-(iPr)2)2)(NBu-t)Cl2] (1233373-56-2)

Guidance literature:

In toluene; (Schlenk, N2) toluene was slowly added to the mixt. of complexes cooled to -72°C, the soln. was allowed to warm to room temp., stirred overnight; volatiles were removed under vac., extd. with hot hexane, concd., crystd. from hot hexane (65°C -> -35°C), filtered, dried under vac.; elem. anal.;

DOI:10.1021/om1001827

Reference yield: 16.0%

[Nb(HC(C(Me)NC6H3-2,6-(iPr)2)2)(NBu-t)Cl3(py)] (1233373-52-8) → [Nb(HC(C(Me)NC6H3-2,6-(iPr)2)2)(NBu-t)Cl2] (1233373-56-2)

Guidance literature:

With B(C₆F₅)3; In benzene; byproducts: pyridine*B(C6F5)3; (Schlenk, N2) to a soln. of complex in C6H6 was added a soln. of B(C6F5)3 in C6H6, the soln. was stirred for 30 min; volatiles were removed under vac., pentane was added, agitated, volatiles were removed under vac., the residue was extd. with pentane, stored at-35°C, redissolved in min pentane, filtered, stored at -35.degre e.C, repeated several times;

DOI:10.1021/om1001827

upstream raw materials:

[Nb(HC(C(Me)NC₆H₃-2,6-(iPr)2)2)(NBu-t)Cl₃(py)]

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 1233373-56-2 [Nb(HC(C(Me)NC₆H₃-2,6-(iPr)2)2)(NBu-t)Cl₂]

Send

Send

Metric Ton KG G Pound L ML

Send

Send