[Rh(anthranilate)(CO)2]

Base Information

• Chemical Name: [Rh(anthranilate)(CO)2]
• CAS No.: 74624-82-1
• Molecular Formula: C₉H₆NO₄Rh
• Molecular Weight: 295.056
• Mol file: 74624-82-1.mol

Synonyms:

Chemical Property of [Rh(anthranilate)(CO)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Rh(anthranilate)(CO)2]

There total 1 articles about [Rh(anthranilate)(CO)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

rhodium(III) chloride trihydrate + anthranilic acid (118-92-3,159201-01-1,50816-84-7,80206-34-4,104809-47-4) → [Rh(H2NC6H4COO)(CO)2] (74624-82-1)

Guidance literature:

In N,N-dimethyl-formamide; soln. of RhCl3*3H2O in DMF treated with 2-fold excess of anthranilic acid; mixt. heated under reflux for 2 h; cooled to about 20°C; diluted with double vol. of H2O; ppt. sepd.; soln. and ppt. cooled to 5°C for 1 h; filtered off; washed (H2O and CH3CO); dried in vac.;

DOI:10.1006/jcat.2002.3665

Reference yield:

[Rh(anthranilate)(CO)2] (74624-82-1) + nitrobenzene (98-95-3,26969-40-4) → [Rh(anthranilate)(PhNO2)(μ-CO)]2

Guidance literature:

With chloroform; In N,N-dimethyl-formamide; stirring (12 h, under (N2)), addition (choroform), kept (48 h, 0°C); washing (chloroform), drying (vac.); elem. anal.;

upstream raw materials:

anthranilic acid