trans-[Ru(isopropyldithiocarbonate)2(triphenylphosphine)2](PF₆)*H₂O

Base Information

• Chemical Name: trans-[Ru(isopropyldithiocarbonate)2(triphenylphosphine)2](PF₆)*H₂O
• CAS No.: 878388-61-5
• Molecular Formula: C₄₄H₄₄O₂P₂RuS₄*F₆P*H₂O
• Molecular Weight: 1059.09
• Mol file: 878388-61-5.mol

Synonyms:

Chemical Property of trans-[Ru(isopropyldithiocarbonate)2(triphenylphosphine)2](PF₆)*H₂O

Chemical Property:

Purity/Quality:

Safty Information:

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Useful:

Technology Process of trans-[Ru(isopropyldithiocarbonate)2(triphenylphosphine)2](PF₆)*H₂O

There total 1 articles about trans-[Ru(isopropyldithiocarbonate)2(triphenylphosphine)2](PF₆)*H₂O which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ammonium hexafluorophosphate + cis-bis(O-i-propyldithiocarbonato)bis(triphenylphosphine)ruthenium(II) → trans-[Ru(isopropyldithiocarbonate)2(triphenylphosphine)2](PF6)*H2O (878388-61-5)

Guidance literature:

With ceric ammonium nitrate; In dichloromethane; water; acetone; to soln. Ru(II) complex and NH4PF6 in acetone-CH2Cl2 (5:1) aq. soln. ceric ammonium nitrate was added and stirred for 10 min; ppt. was filtered and washed with water, recrystn. from CH2Cl2-Et2O; elem. anal.;

DOI:10.1021/ic051487l