[chloro(η(5)-cyclopentadienyl)bis(mesitylimido)tungsten(VI)]

Base Information

Chemical Name:[chloro(η(5)-cyclopentadienyl)bis(mesitylimido)tungsten(VI)]
CAS No.:354589-28-9
Molecular Formula:C₂₃H₂₇ClN₂W
Molecular Weight:550.784
Hs Code.:

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Chemical Property of [chloro(η(5)-cyclopentadienyl)bis(mesitylimido)tungsten(VI)]

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Technology Process of [chloro(η(5)-cyclopentadienyl)bis(mesitylimido)tungsten(VI)]

There total 1 articles about [chloro(η(5)-cyclopentadienyl)bis(mesitylimido)tungsten(VI)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: [bis(mesitylimido)-dichloro-(dimethoxyethane)tungsten(VI)]

: 16733-97-4
cyclopentadienyllithium

: 354589-28-9
[chloro(η(5)-cyclopentadienyl)bis(mesitylimido)tungsten(VI)]

Guidance literature:: In diethyl ether; all manipulations under Ar; complex added to suspn. of C5H5Li at -78°C, allowed to warm to room temp. in 30 min and standing for 2 h; all volatiles removed, residue dried at 50°C, extd. with toluene,soln. concd., product pptd. with hexane, filtered, dried in vac.; elem. anal.;
DOI:10.1002/1099-0682(200106)2001:6<1617::AID-EJIC1617>3.0.CO;2-B

Reference yield: 80.0%

: 354589-28-9
[chloro(η(5)-cyclopentadienyl)bis(mesitylimido)tungsten(VI)]

: 591-51-5
phenyllithium

: 752995-15-6
[(η(5)-C5H5W(N-mesitylimido)2Ph]

Guidance literature:: In hexane; toluene; under Ar, 2.0 M hexane soln. of PhLi was added to toluene soln. of W-complex at -78 °C, warming to room temp. in 30 min, stirring for 24 h; evapn. to dryness in vac., extn. with toluene, filtration through Celite, evapn., keeping in high vac. (30 °C/1E-5 bar), elem. anal.;
DOI:10.1002/zaac.200400016