2,2,2-Trichloro-acetimidic acid (2R,4aR,7R,8R,8aS)-8-benzyloxy-7-(3,4-dimethyl-2,5-dioxo-2,5-dihydro-pyrrol-1-yl)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl ester

Base Information

Chemical Name:2,2,2-Trichloro-acetimidic acid (2R,4aR,7R,8R,8aS)-8-benzyloxy-7-(3,4-dimethyl-2,5-dioxo-2,5-dihydro-pyrrol-1-yl)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl ester
CAS No.:666728-56-9
Molecular Formula:C₂₈H₂₇Cl₃N₂O₇
Molecular Weight:609.891
Hs Code.:

2,2,2-Trichloro-acetimidic acid (2R,4aR,7R,8R,8aS)-8-benzyloxy-7-(3,4-dimethyl-2,5-dioxo-2,5-dihydro-pyrrol-1-yl)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl ester

Synonyms:

Suppliers and Price of 2,2,2-Trichloro-acetimidic acid (2R,4aR,7R,8R,8aS)-8-benzyloxy-7-(3,4-dimethyl-2,5-dioxo-2,5-dihydro-pyrrol-1-yl)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2,2,2-Trichloro-acetimidic acid (2R,4aR,7R,8R,8aS)-8-benzyloxy-7-(3,4-dimethyl-2,5-dioxo-2,5-dihydro-pyrrol-1-yl)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2,2,2-Trichloro-acetimidic acid (2R,4aR,7R,8R,8aS)-8-benzyloxy-7-(3,4-dimethyl-2,5-dioxo-2,5-dihydro-pyrrol-1-yl)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl ester

There total 4 articles about 2,2,2-Trichloro-acetimidic acid (2R,4aR,7R,8R,8aS)-8-benzyloxy-7-(3,4-dimethyl-2,5-dioxo-2,5-dihydro-pyrrol-1-yl)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 81927-55-1
O-benzyl 2,2,2-trichloroacetimidate

: 666728-56-9
2,2,2-Trichloro-acetimidic acid (2R,4aR,7R,8R,8aS)-8-benzyloxy-7-(3,4-dimethyl-2,5-dioxo-2,5-dihydro-pyrrol-1-yl)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 67 percent / 4 Angstroem molecular sieves; CF₃SO₃H / CH₂Cl₂; hexane / 1 h / cooling

2: 72 percent / Bu₄NF / tetrahydrofuran / 4 h / -20 °C

3: DBU / CH₂Cl₂ / 2 h

With trifluorormethanesulfonic acid; 4 A molecular sieve; tetrabutyl ammonium fluoride; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1021/jo035397e

Reference yield:

: 216877-67-7
tert-butyldimethylsilyl 4,6-O-benzylidene-2-deoxy-2-dimethylmaleoyl-β-D-glucopyranoside

: 666728-56-9
2,2,2-Trichloro-acetimidic acid (2R,4aR,7R,8R,8aS)-8-benzyloxy-7-(3,4-dimethyl-2,5-dioxo-2,5-dihydro-pyrrol-1-yl)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 67 percent / 4 Angstroem molecular sieves; CF₃SO₃H / CH₂Cl₂; hexane / 1 h / cooling

2: 72 percent / Bu₄NF / tetrahydrofuran / 4 h / -20 °C

3: DBU / CH₂Cl₂ / 2 h

With trifluorormethanesulfonic acid; 4 A molecular sieve; tetrabutyl ammonium fluoride; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1021/jo035397e

Reference yield:

: 666728-54-7
tert-butyl(dimethyl)silyl 3-O-benzyl-4,6-O-benzylidene-2-dimethylmaleimido-2-deoxy-β-D-glucopyranoside

: 666728-56-9
2,2,2-Trichloro-acetimidic acid (2R,4aR,7R,8R,8aS)-8-benzyloxy-7-(3,4-dimethyl-2,5-dioxo-2,5-dihydro-pyrrol-1-yl)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 72 percent / Bu₄NF / tetrahydrofuran / 4 h / -20 °C

2: DBU / CH₂Cl₂ / 2 h

With tetrabutyl ammonium fluoride; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo035397e