6aα,12aα-dihydro-6α-methyl-1-phenylspirofuran-12(7H),2'-<1,3>dithiolan>-6β-ol

Base Information

Chemical Name:6aα,12aα-dihydro-6α-methyl-1-phenylspirofuran-12(7H),2'-<1,3>dithiolan>-6β-ol
CAS No.:66314-58-7
Molecular Formula:C₂₈H₂₄O₂S₂
Molecular Weight:456.629
Hs Code.:

6aα,12aα-dihydro-6α-methyl-1-phenylspiro<naphthaceno<1,12-bc>furan-12(7H),2'-<1,3>dithiolan>-6β-ol

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Chemical Property of 6aα,12aα-dihydro-6α-methyl-1-phenylspirofuran-12(7H),2'-<1,3>dithiolan>-6β-ol

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Technology Process of 6aα,12aα-dihydro-6α-methyl-1-phenylspirofuran-12(7H),2'-<1,3>dithiolan>-6β-ol

There total 1 articles about 6aα,12aα-dihydro-6α-methyl-1-phenylspirofuran-12(7H),2'-<1,3>dithiolan>-6β-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

: 917-54-4
methyllithium

: 33133-90-3
6aα,12aα-dihydro-1-phenylspirofuran-12(7H),2'-<1,3>dithiolan>-6-one

: 66314-58-7,76024-35-6
6aα,12aα-dihydro-6α-methyl-1-phenylspirofuran-12(7H),2'-<1,3>dithiolan>-6β-ol

Guidance literature:: In tetrahydrofuran; diethyl ether; at -78 ℃;
DOI:10.1039/P19810001840

Reference yield: 78.0%

: 66314-58-7,76024-35-6
6aα,12aα-dihydro-6α-methyl-1-phenylspirofuran-12(7H),2'-<1,3>dithiolan>-6β-ol

: 33133-74-3,76024-36-7
cis-6aα,12aα-dihydro-6β-hydroxy-6α-methyl-1-phenylnaphthaceno<1,12-bc>furan-12(6H,7H)-one

Guidance literature:: With pyridine; benzeneseleninic anhydride; In tetrahydrofuran; at 40 ℃; for 50h;
DOI:10.1039/P19810001840

Reference yield:

: 66314-58-7,76024-35-6
6aα,12aα-dihydro-6α-methyl-1-phenylspirofuran-12(7H),2'-<1,3>dithiolan>-6β-ol

: 5,5aα,6,11,11aα,12-hexahydro-5β-hydroxy-5α-methyl-11,12-dioxonaphthacen-1-yl benzoate

Guidance literature:: Multi-step reaction with 2 steps

1: 78 percent / benzeneseleninic anhydride, pyridine / tetrahydrofuran / 50 h / 40 °C

2: 1.) O₃, 2.) dimethyl sulphide / 1.) CHCl₃, MeOH, pyridine, -78 deg C, 3 h, 2.) -78 deg C -> room temperature

With pyridine; dimethylsulfide; benzeneseleninic anhydride; ozone; In tetrahydrofuran;
DOI:10.1039/P19810001840