trans-{FeH(CO)(P(OEt)3)4}BPh₄

Base Information

Chemical Name:trans-{FeH(CO)(P(OEt)3)4}BPh₄
CAS No.:95738-79-7
Molecular Formula:C₂₄H₂₀B*C₂₅H₆₁FeO₁₃P₄
Molecular Weight:1068.73
Hs Code.:

trans-{FeH(CO)(P(OEt)3)4}BPh<sub>4</sub>

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Chemical Property of trans-{FeH(CO)(P(OEt)3)4}BPh₄

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Technology Process of trans-{FeH(CO)(P(OEt)3)4}BPh₄

There total 1 articles about trans-{FeH(CO)(P(OEt)3)4}BPh₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 100112-87-6
[Fe(Cl)(CO)(P(OEt)3)4]BPh₄

: 95738-79-7
trans-{FeH(CO)(P(OEt)3)4}BPh₄

Guidance literature:: With Zn; In acetonitrile; under inert atmosphere; zinc dust in excess added to a soln. of Fe-complex; stirred until the soln. turned colorless; filtered; evapd.; stirred with ethanol or methanol for 1 h; crystd. from alcohol; elem. anal.;

Reference yield:

: 95738-79-7
trans-{FeH(CO)(P(OEt)3)4}BPh₄

: 108945-67-1
(Fe(C₅H₅N)(CO)(P(OC₂H₅)3)4)⁽²⁺⁾*2B(C₆H₅)4^(1-)=(Fe(C₅H₅N)(CO)(P(OC₂H₅)3)4)(B(C₆H₅)4)2

Guidance literature:: With pyridine; (4-CH₃C₆H₄N₂)BF₄; NaBPh₄; In dichloromethane; to a soln. of Fe-compd. (1 mmol) in CH2Cl2 was added a slight excess of (4-CH3C6H4N2)BF4 (1.5 mmol) and the react. mixt. was stirred at room temp. under an inert atmosphere for 24 h; an excess of amine (3 mmol) in CH2Cl2 was added, stirring for 20 h; the solvent was removed under reduced pressure to give a brown oil, which was triturated with ethanol; the addn. of NaBPh4 afforded a yellow solid, which was filtered and twice crystd. from CH2Cl2/ethanol;;

Reference yield:

: 75-18-3
dimethylsulfide

: 95738-79-7
trans-{FeH(CO)(P(OEt)3)4}BPh₄

: 108968-96-3
(Fe((CH₃)2S)(CO)(P(OC₂H₅)3)4)⁽²⁺⁾*2B(C₆H₅)4^(1-)=(Fe((CH₃)2S)(CO)(P(OC₂H₅)3)4)(B(C₆H₅)4)2

Guidance literature:: With (4-CH₃C₆H₄N₂)BF₄; NaBPh₄; In dichloromethane; to a soln. of Fe-compd. (1 mmol) in CH2Cl2 was added a slight excess of (4-CH3C6H4N2)BF4 (1.5 mmol) and the react. mixt. was stirred at room temp. under an inert atmosphere for 24 h; an excess of sulfide (3 mmol) in CH2Cl2 was added, stirring for 20 h;; the solvent was removed under reduced pressure to give a brown oil, which was triturated with ethanol; the addn. of NaBPh4 afforded a yellow solid, which was filtered and twice crystd. from CH2Cl2/ethanol;;