iodo(hydrido)(methyldiethoxysilyl)bis(triphenylphosphine)rhodium(III)

Base Information

• Chemical Name: iodo(hydrido)(methyldiethoxysilyl)bis(triphenylphosphine)rhodium(III)
• CAS No.: 407584-39-8
• Molecular Formula: C₄₁H₄₄IO₂P₂RhSi
• Molecular Weight: 888.642
• Mol file: 407584-39-8.mol

Synonyms:

Chemical Property of iodo(hydrido)(methyldiethoxysilyl)bis(triphenylphosphine)rhodium(III)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of iodo(hydrido)(methyldiethoxysilyl)bis(triphenylphosphine)rhodium(III)

There total 2 articles about iodo(hydrido)(methyldiethoxysilyl)bis(triphenylphosphine)rhodium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

tris(triphenylphosphine)rhodium(I) iodide (14973-90-1) + diethoxymethylane (2031-62-1) → iodo(hydrido)(methyldiethoxysilyl)bis(triphenylphosphine)rhodium(III) (407584-39-8)

Guidance literature:

In toluene; under N2 or Ar, standard Schlenk techniques; ligand (1 equiv.) added to toluene dispersion of Rh complex at room temp.; stirred for 2 h; concd.; hexane added; filtered; ppt. washed with hexane; dried in vac.; elem. anal.;

DOI:10.1021/om010862o

Reference yield:

diethoxymethylane (2031-62-1) + Triethoxysilane (998-30-1) + iodo(hydrido)(triethoxysilyl)bis(triphenylphosphine)rhodium(III) (25929-99-1,409099-76-9) → iodo(hydrido)(methyldiethoxysilyl)bis(triphenylphosphine)rhodium(III) (407584-39-8)

Guidance literature:

In ⁽²⁾H₈-toluene; under N2 or Ar, standard Schlenk techniques; in NMR tube; equimolar mixt. of HSi(OEt)2Me and HSi(OEt)3 (excess) added to soln. of Rh complex in toluene-d8; sealed; heated at 50°C (oil bath) for 2 h; kept at fixed temp. (278-318 K) for 30 min; not isolated; monitored by (1)H NMR spectra; equil. mixt. of the starting Rh-Si(OEt)3 complex and resultant Rh-Si(OEt)2Me complex obtained;

DOI:10.1021/om010862o

upstream raw materials:

diethoxymethylane

Triethoxysilane

iodo(hydrido)(triethoxysilyl)bis(triphenylphosphine)rhodium(III)

tris(triphenylphosphine)rhodium(I) iodide