[(η5-pentamethylcyclopentadiene)Pt(CO)((Z)-3-ethenyl-1,2-diphenylcyclopropene)]

Base Information

Chemical Name:[(η5-pentamethylcyclopentadiene)Pt(CO)((Z)-3-ethenyl-1,2-diphenylcyclopropene)]
CAS No.:677736-11-7
Molecular Formula:C₂₈H₂₈OPt
Molecular Weight:575.61
Hs Code.:

Synonyms:

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Chemical Property of [(η5-pentamethylcyclopentadiene)Pt(CO)((Z)-3-ethenyl-1,2-diphenylcyclopropene)]

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Technology Process of [(η5-pentamethylcyclopentadiene)Pt(CO)((Z)-3-ethenyl-1,2-diphenylcyclopropene)]

There total 1 articles about [(η5-pentamethylcyclopentadiene)Pt(CO)((Z)-3-ethenyl-1,2-diphenylcyclopropene)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 14.0%

: 677736-10-6
[PtI(η5-pentamethylcyclopentadienyl)(CO)]

: 223248-78-0
(Z)-(3-(2-iodovinyl)cycloprop-1-ene-1,2-diyl)dibenzene

: (η5-pentamethylcyclopentadienyl)[PtC5H3Ph2]

: 677736-11-7
[(η5-pentamethylcyclopentadiene)Pt(CO)((Z)-3-ethenyl-1,2-diphenylcyclopropene)]

Guidance literature:: With BuLi; In diethyl ether; hexane; under Ar; cyclopropene dissolved in dry Et2O; cooled to -78°C; BuLi in hexanes added dropwise; stirred at -78°C for 15 min; added to cooled (-50°C) flask contg. Pt complex; warmed to -20°C; stirred fo 12 h; evapd.; chromd. (silica, hexanes-EtOAc 30:1 to 9:1); yellow band concd.;another Pt complex obtained by evapn. of red band; elem. anal.;
DOI:10.1021/om900439z

Reference yield:

: 677736-11-7
[(η5-pentamethylcyclopentadiene)Pt(CO)((Z)-3-ethenyl-1,2-diphenylcyclopropene)]

: (η5-pentamethylcyclopentadienyl)[PtC5H3Ph2]

Guidance literature:: In benzene-d6; under Ar; in NMR tube; Pt complex dissolved in C6D6; 36-48 h at room temp.; monitored by (1)H NMR spectra;
DOI:10.1021/om900439z