(Sp)-2-(diphenylphosphino)-1-(prop-1-en-1-yl)ferrocene

Base Information

• Chemical Name: (Sp)-2-(diphenylphosphino)-1-(prop-1-en-1-yl)ferrocene
• CAS No.: 913237-60-2
• Molecular Formula: C₂₅H₂₃FeP
• Molecular Weight: 410.278
• Mol file: 913237-60-2.mol

Synonyms:

Chemical Property of (Sp)-2-(diphenylphosphino)-1-(prop-1-en-1-yl)ferrocene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (Sp)-2-(diphenylphosphino)-1-(prop-1-en-1-yl)ferrocene

There total 1 articles about (Sp)-2-(diphenylphosphino)-1-(prop-1-en-1-yl)ferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

(S)-α-(diphenylphosphino)ferrocenecarboxaldehyde + ethyltriphenylphosphonium bromide (1530-32-1) → (Sp)-2-(diphenylphosphino)-1-(prop-1-en-1-yl)ferrocene (913237-60-2,913095-09-7)

Guidance literature:

With butyllithium; In tetrahydrofuran; hexane; under Ar atm. n-BuLi in hexane was added slowly to suspn. Ph3PEtBr in THF at 0°C and stirred at 0°C for 15 min, soln. Fe complex in THF was added and stirred at 0°C for 30 min and at 60°C overnight; react. mixt. was quenched with aq. NaCl, diluted with Et2O, org. phase was separated, washed with brine, dried over MgSO4, evapd. in vacuo, residue was purified by column chromy. on silica (hexane-Et2O 10:1), crystn.from warm heptane; mixt. Z/E isomers;

DOI:10.1021/ic061278g

Reference yield: 44.0%

carbonyhltungsten(0)(cycloocta-1,5-diene) (12129-70-3) + (Sp)-2-(diphenylphosphino)-1-(prop-1-en-1-yl)ferrocene (913237-60-2,913095-09-7) → tetracarbonyl[(Sp)-2-(diphenylphosphino-κP)-1-(η(1,2)-prop-1-en-1-yl)ferrocene]tungsten(0) (913237-59-9,913095-16-6)

Guidance literature:

In toluene; under Ar atm. Fe and W complexes in toluene was heated under reflux for 3 h; soln. was cooled to room temp., filtered through silica, and evapd. in vacuo, residue was purified by column chromy. on silica (hexane-Et2O 10:1), dissolved in boiling heptane, filtered, left at 0°C, ppt. was dried in vacuo; mixt. Z/E isomers;

DOI:10.1021/ic061278g

upstream raw materials:

ethyltriphenylphosphonium bromide

Downstream raw materials:

tetracarbonyl[(Sp)-2-(diphenylphosphino-κP)-1-(η(1,2)-prop-1-en-1-yl)ferrocene]tungsten(0)