2-hexyl thiirane

Base Information

• Chemical Name: 2-hexyl thiirane
• CAS No.: 58396-31-9
• Molecular Formula: C₈H₁₆S
• Molecular Weight: 144.281
• Mol file: 58396-31-9.mol

Synonyms:

Chemical Property of 2-hexyl thiirane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-hexyl thiirane

There total 11 articles about 2-hexyl thiirane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

1,2-Epoxyoctane (2984-50-1) → 2-hexyl thiirane (5633-78-3,58396-31-9,58437-20-0)

Guidance literature:

With tin(IV)tetraphenylporphyrinato trifluoromethanesulfonate; ammonium thiocyanate; In acetonitrile; for 0.666667h; Heating;

DOI:10.1016/j.tet.2004.05.069

Reference yield: 87.0%

2-iodo-1-thiocyanato-octane (83048-90-2) → 2-hexyl thiirane (5633-78-3,58396-31-9,58437-20-0)

Guidance literature:

With lithium triethylborohydride; In tetrahydrofuran; for 2h; Ambient temperature;

Reference yield: 73.0%

5-hexyl-1,3-oxathiolane-2-thione (96738-42-0) → 2-hexyl thiirane (5633-78-3,58396-31-9,58437-20-0) + 5-hexyl-1,3-oxathiolane-2-one + 4-hexyl-1,3-dithiolane-2-thione

Guidance literature:

With carbon disulfide; tetradecane; triethylamine; at 100 ℃; for 20h; under 6000480 Torr; sealed teflon tube;

DOI:10.1246/bcsj.62.474

upstream raw materials:

2-iodo-1-thiocyanato-octane

carbon disulfide

1,2-Epoxyoctane

5-hexyl-1,3-oxathiolane-2-thione

Downstream raw materials:

1-octen-1-yl phenyl sulfide

octane-2-thiol

1-N,N-dibenzylaminooctane-2-sulfonic acid

1-N,N-dibenzylamino-2-octylmercaptan