Technology Process of ethyl (1RS,6RS)<3,6-bis(tert-butyldimethylsiloxy)-2-cyclohexen-1-yl>acetate
There total 4 articles about ethyl (1RS,6RS)<3,6-bis(tert-butyldimethylsiloxy)-2-cyclohexen-1-yl>acetate which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 4 steps
1: mCPBA / CH2Cl2 / 14 h / Ambient temperature
2: basic alumina / CH2Cl2; diethyl ether / 1 h
3: 92 percent / DBU / benzene / 1.5 h / Ambient temperature
4: 1.) HgI2 / 1.) room temp., 15 min, 2.) - 78 deg C, 2 h
With
aluminum oxide; 1,8-diazabicyclo[5.4.0]undec-7-ene; 3-chloro-benzenecarboperoxoic acid; mercury(II) iodide;
In
diethyl ether; dichloromethane; benzene;
DOI:10.1021/ja00189a038
- Guidance literature:
-
Multi-step reaction with 2 steps
1: 92 percent / DBU / benzene / 1.5 h / Ambient temperature
2: 1.) HgI2 / 1.) room temp., 15 min, 2.) - 78 deg C, 2 h
With
1,8-diazabicyclo[5.4.0]undec-7-ene; mercury(II) iodide;
In
benzene;
DOI:10.1021/ja00189a038
- Guidance literature:
-
Multi-step reaction with 3 steps
1: basic alumina / CH2Cl2; diethyl ether / 1 h
2: 92 percent / DBU / benzene / 1.5 h / Ambient temperature
3: 1.) HgI2 / 1.) room temp., 15 min, 2.) - 78 deg C, 2 h
With
aluminum oxide; 1,8-diazabicyclo[5.4.0]undec-7-ene; mercury(II) iodide;
In
diethyl ether; dichloromethane; benzene;
DOI:10.1021/ja00189a038
