Trifluoro-methanesulfonic acid (2R,3S,6S)-3-[dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-6-(2-methyl-cyclohex-2-enyl)-3,6-dihydro-2H-pyran-2-ylmethyl ester

Base Information

Chemical Name:Trifluoro-methanesulfonic acid (2R,3S,6S)-3-[dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-6-(2-methyl-cyclohex-2-enyl)-3,6-dihydro-2H-pyran-2-ylmethyl ester
CAS No.:188199-02-2
Molecular Formula:C₂₂H₃₇F₃O₅SSi
Molecular Weight:498.679
Hs Code.:

Trifluoro-methanesulfonic acid (2R,3S,6S)-3-[dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-6-(2-methyl-cyclohex-2-enyl)-3,6-dihydro-2H-pyran-2-ylmethyl ester

Synonyms:

Suppliers and Price of Trifluoro-methanesulfonic acid (2R,3S,6S)-3-[dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-6-(2-methyl-cyclohex-2-enyl)-3,6-dihydro-2H-pyran-2-ylmethyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Trifluoro-methanesulfonic acid (2R,3S,6S)-3-[dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-6-(2-methyl-cyclohex-2-enyl)-3,6-dihydro-2H-pyran-2-ylmethyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Trifluoro-methanesulfonic acid (2R,3S,6S)-3-[dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-6-(2-methyl-cyclohex-2-enyl)-3,6-dihydro-2H-pyran-2-ylmethyl ester

There total 5 articles about Trifluoro-methanesulfonic acid (2R,3S,6S)-3-[dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-6-(2-methyl-cyclohex-2-enyl)-3,6-dihydro-2H-pyran-2-ylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 358-23-6
trifluoromethylsulfonic anhydride

: 188199-01-1
[(2R,3S,6S)-3-[Dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-6-(2-methyl-cyclohex-2-enyl)-3,6-dihydro-2H-pyran-2-yl]-methanol

: 188199-02-2
Trifluoro-methanesulfonic acid (2R,3S,6S)-3-[dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-6-(2-methyl-cyclohex-2-enyl)-3,6-dihydro-2H-pyran-2-ylmethyl ester

Guidance literature:: With pyridine; In dichloromethane; at -15 ℃; for 1.5h;
DOI:10.1016/S0968-0896(96)00224-6

Reference yield:

: 67373-56-2
chlorodimethyl(1,1,2-trimethylpropyl)silane

: 188199-02-2
Trifluoro-methanesulfonic acid (2R,3S,6S)-3-[dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-6-(2-methyl-cyclohex-2-enyl)-3,6-dihydro-2H-pyran-2-ylmethyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: imidazole, DMAP / dimethylformamide

2: 80 percent / aq. HCO₂H / diethyl ether / 0.5 h

3: pyridine / CH₂Cl₂ / 1.5 h / -15 °C

With pyridine; 1H-imidazole; dmap; formic acid; In diethyl ether; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/S0968-0896(96)00224-6

Reference yield:

: [2S,5α,6β]-1-(5,6-dihydro-6-hydroxymethyl-5-hydroxy-2H-pyran-2-yl)-2-methyl-cyclohex-2-ene

: 188199-02-2
Trifluoro-methanesulfonic acid (2R,3S,6S)-3-[dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-6-(2-methyl-cyclohex-2-enyl)-3,6-dihydro-2H-pyran-2-ylmethyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 75 percent / pyridine, DMAP / CH₂Cl₂ / 2.5 h

2: imidazole, DMAP / dimethylformamide

3: 80 percent / aq. HCO₂H / diethyl ether / 0.5 h

4: pyridine / CH₂Cl₂ / 1.5 h / -15 °C

With pyridine; 1H-imidazole; dmap; formic acid; In diethyl ether; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/S0968-0896(96)00224-6