[4-2,6-diisopropylphenyl-amino-pent-3-en-2-ylidene-amino-benzonitrilate k-²N,N’](η³-methallyl)nickel (II) tris(pentafluorophenyl)boron

Base Information

• Chemical Name: [4-2,6-diisopropylphenyl-amino-pent-3-en-2-ylidene-amino-benzonitrilate k-²N,N’](η³-methallyl)nickel (II) tris(pentafluorophenyl)boron
• CAS No.: 1501943-26-5
• Molecular Formula: C₄₆H₃₅BF₁₅N₃Ni
• Molecular Weight: 984.281
• Mol file: 1501943-26-5.mol

Synonyms:

Chemical Property of [4-2,6-diisopropylphenyl-amino-pent-3-en-2-ylidene-amino-benzonitrilate k-²N,N’](η³-methallyl)nickel (II) tris(pentafluorophenyl)boron

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [4-2,6-diisopropylphenyl-amino-pent-3-en-2-ylidene-amino-benzonitrilate k-²N,N’](η³-methallyl)nickel (II) tris(pentafluorophenyl)boron

There total 4 articles about [4-2,6-diisopropylphenyl-amino-pent-3-en-2-ylidene-amino-benzonitrilate k-²N,N’](η³-methallyl)nickel (II) tris(pentafluorophenyl)boron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

[4-2,6-diisopropylphenyl-amino-pent-3-en-2-ylidene-amino-benzonitrilate k-2N,N’](η3-methallyl) nickel (II) (1501943-20-9) + tris(pentafluorophenyl)borate (1109-15-5) → [4-2,6-diisopropylphenyl-amino-pent-3-en-2-ylidene-amino-benzonitrilate k-2N,N’](η3-methallyl)nickel (II) tris(pentafluorophenyl)boron (1501943-26-5)

Guidance literature:

In toluene; for 0.166667h;

DOI:10.1021/om400847b

Reference yield:

4-((2,6-diisopropylphenyl)imino)pentan-2-one (471247-65-1) → [4-2,6-diisopropylphenyl-amino-pent-3-en-2-ylidene-amino-benzonitrilate k-2N,N’](η3-methallyl)nickel (II) tris(pentafluorophenyl)boron (1501943-26-5)

Guidance literature:

Multi-step reaction with 3 steps

1.1: toluene-4-sulfonic acid / toluene / 96 h / Reflux; Dean-Stark

2.1: potassium hydride / diethyl ether / 12 h

2.2: 4 h / 20 °C

3.1: toluene / 0.17 h

With potassium hydride; toluene-4-sulfonic acid; In diethyl ether; toluene;

DOI:10.1021/om400847b

Reference yield:

N-phenyl-2-cyano-N-2,6-diisopropylphenyl-β-diketiminate → [4-2,6-diisopropylphenyl-amino-pent-3-en-2-ylidene-amino-benzonitrilate k-2N,N’](η3-methallyl)nickel (II) tris(pentafluorophenyl)boron (1501943-26-5)

Guidance literature:

Multi-step reaction with 2 steps

1.1: potassium hydride / diethyl ether / 12 h

1.2: 4 h / 20 °C

2.1: toluene / 0.17 h

With potassium hydride; In diethyl ether; toluene;

DOI:10.1021/om400847b

upstream raw materials:

[4-2,6-diisopropylphenyl-amino-pent-3-en-2-ylidene-amino-benzonitrilate k-²N,N’](η³-methallyl) nickel (II)

tris(pentafluorophenyl)borate

anthranilic acid nitrile

4-((2,6-diisopropylphenyl)imino)pentan-2-one