t-Butyl 5β--3α,4α-dihydroxy-6α-trifluoromethylcyclohex-1-ene carboxylate

Base Information

Chemical Name:t-Butyl 5β--3α,4α-dihydroxy-6α-trifluoromethylcyclohex-1-ene carboxylate
CAS No.:130130-78-8
Molecular Formula:C₁₈H₃₁F₃O₅Si
Molecular Weight:412.522
Hs Code.:

t-Butyl 5β-<dimethyl(t-butyl)silyloxy>-3α,4α-dihydroxy-6α-trifluoromethylcyclohex-1-ene carboxylate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of t-Butyl 5β--3α,4α-dihydroxy-6α-trifluoromethylcyclohex-1-ene carboxylate

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Technology Process of t-Butyl 5β--3α,4α-dihydroxy-6α-trifluoromethylcyclohex-1-ene carboxylate

There total 9 articles about t-Butyl 5β--3α,4α-dihydroxy-6α-trifluoromethylcyclohex-1-ene carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 130130-77-7,130130-86-8
t-Butyl 5β--6α-trifluoromethyl-cyclohexa-1,3-diene carboxylate

: 130130-78-8,130194-74-0
t-Butyl 5β--3α,4α-dihydroxy-6α-trifluoromethylcyclohex-1-ene carboxylate

Guidance literature:: With pyridine; osmium(VIII) oxide; for 8h; Ambient temperature;
DOI:10.1039/P19900001281

Reference yield: 45.0%

: 130130-77-7,130130-86-8
t-Butyl 5β--6β-trifluoromethyl-cyclohexa-1,3-diene-carboxylate

: 130130-78-8,130194-74-0
t-Butyl 5β--3α,4α-dihydroxy-6β-trifluoromethylcyclohex-1-ene carboxylate

Guidance literature:: With pyridine; osmium(VIII) oxide; In diethyl ether; for 15h; Ambient temperature;
DOI:10.1039/P19900001281

Reference yield:

: 136383-21-6,78762-71-7
trans-tert-butyl 4,4,4-trifluorocrotonate

: 130130-78-8,130194-74-0
t-Butyl 5β--3α,4α-dihydroxy-6β-trifluoromethylcyclohex-1-ene carboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: 64 h / 80 °C

2: 95 percent / 2,6-lutidine / CH₂Cl₂ / 0.75 h / 0 °C

3: 45 percent / OsO₄, pyridine / diethyl ether / 15 h / Ambient temperature

With pyridine; 2,6-dimethylpyridine; osmium(VIII) oxide; In diethyl ether; dichloromethane;
DOI:10.1039/P19900001281