5,17-Bis(2-propenyl)calix[4]arene

Base Information

• Chemical Name: 5,17-Bis(2-propenyl)calix[4]arene
• CAS No.: 125065-75-0
• Molecular Formula: C₃₄H₃₂O₄
• Molecular Weight: 504.626
• European Community (EC) Number: 603-028-7
• DSSTox Substance ID: DTXSID201227623
• Nikkaji Number: J949.186D
• Mol file: 125065-75-0.mol

Synonyms:DTXSID201227623;5,17-Bis(2-propenyl)calix[4]arene;5,17-Diallyl-25,26,27,28-tetrahydroxycalix[4]arene;125065-75-0

Chemical Property of 5,17-Bis(2-propenyl)calix[4]arene

Chemical Property:

• XLogP3: 8.4
• Hydrogen Bond Donor Count: 4
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 4
• Exact Mass: 504.23005950
• Heavy Atom Count: 38
• Complexity: 670

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C=CCC1=CC2=C(C(=C1)CC3=C(C(=CC=C3)CC4=CC(=CC(=C4O)CC5=CC=CC(=C5O)C2)CC=C)O)O

Technology Process of 5,17-Bis(2-propenyl)calix[4]arene

There total 1 articles about 5,17-Bis(2-propenyl)calix[4]arene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 7.0%

25,27-Bis(phenylmethoxy)-26,28-bis(2-propenyloxy)pentacyclo<19.3.1.13,7.19,13.115,19>octacosa-1(25),3,5,7(28),9,11,13(27),15,17,19(26),21,23-dodecaene (125065-82-9,129568-42-9) → 5,17-bis(2-propenyl)-25,26,27,28-tetrahydroxycalix[4]arene (125065-75-0,129568-44-1) + 26,28-Bis(phenylmethoxy)-11,23-di-2-propenylpentacyclo<19.3.1.13,7.19,13.115,19>octacosa-1(25),3,5,7(28),9,11,13(27),15,17,19(26),21,23-dodecaene-25,27-diol (125065-74-9,129568-43-0)

Guidance literature:

In various solvent(s); Heating;

DOI:10.1016/S0040-4039(00)99097-X

Reference yield: 87.0%

5,17-bis(2-propenyl)-25,26,27,28-tetrahydroxycalix[4]arene (125065-75-0,129568-44-1) + N-hydroxy-4-methoxy-benzenecarboximidoyl chloride (38435-51-7) → C50H46N2O8

Guidance literature:

With triethylamine; In acetonitrile; for 24h; Heating;

DOI:10.1002/jccs.200000020

Reference yield: 83.0%

5,17-bis(2-propenyl)-25,26,27,28-tetrahydroxycalix[4]arene (125065-75-0,129568-44-1) + N-hydroxy-4-methoxy-benzenecarboximidoyl chloride (38435-51-7) → C42H39NO6

Guidance literature:

With triethylamine; In acetonitrile; for 12h; Heating;

DOI:10.1002/jccs.200000020

upstream raw materials:

25,27-Bis(phenylmethoxy)-26,28-bis(2-propenyloxy)pentacyclo<19.3.1.1^3,7.1^9,13.1^15,19>octacosa-1(25),3,5,7(28),9,11,13(27),15,17,19(26),21,23-dodecaene