trans-(Pt(Ph₂P(CH₂)11PPh₂)Cl₂)2

Base Information

• Chemical Name: trans-(Pt(Ph₂P(CH₂)11PPh₂)Cl₂)2
• CAS No.: 83149-29-5
• Molecular Formula: C₇₀H₈₄Cl₄P₄Pt₂
• Molecular Weight: 1581.3
• Mol file: 83149-29-5.mol

Synonyms:

Chemical Property of trans-(Pt(Ph₂P(CH₂)11PPh₂)Cl₂)2

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of trans-(Pt(Ph₂P(CH₂)11PPh₂)Cl₂)2

There total 1 articles about trans-(Pt(Ph₂P(CH₂)11PPh₂)Cl₂)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

potassium trichloro(ethene)platinate(II) (12012-50-9) + (C6H5)2P(CH2)11P(C6H5)2 (82195-41-3) → trans-Pt(Ph2P(CH2)11PPh2)Cl2 (83149-24-0) + trans-(Pt(Ph2P(CH2)11PPh2)Cl2)2 (83149-29-5)

Guidance literature:

In chloroform; acetone; a soln. of ligand in acetone/CHCl3 was added to a stirred soln. of Pt-complex in acetone over a 30 min period, stirred for 1 h; evapd. to dryness at room temp. in vac., dissolved in CHCl3, filtered, pentane was added, cooled in refrigerator, isolated by fractional crystn., collected by vac. filtration, washed with H2O, EtOH, pentane, dried under vac.; elem. anal.;

DOI:10.1021/ja00386a028

upstream raw materials:

potassium trichloro(ethene)platinate(II)

(C₆H₅)2P(CH₂)11P(C₆H₅)2