{RuCl(P(CH₃)3)2(C₅H₃N(C₃H₂(C₆H₄Cl)N₂)2)}⁽¹⁺⁾*ClO₄^(1-)={RuCl(P(CH₃)3)2(C₅H₃N(C₃H₂(C₆H₄Cl)N₂)2)}ClO₄

Base Information

• Chemical Name: {RuCl(P(CH₃)3)2(C₅H₃N(C₃H₂(C₆H₄Cl)N₂)2)}⁽¹⁺⁾*ClO₄^(1-)={RuCl(P(CH₃)3)2(C₅H₃N(C₃H₂(C₆H₄Cl)N₂)2)}ClO₄
• CAS No.: 150414-17-8
• Molecular Formula: C₂₉H₃₃Cl₃N₅P₂Ru*ClO₄
• Molecular Weight: 820.442

Synonyms:

Chemical Property of {RuCl(P(CH₃)3)2(C₅H₃N(C₃H₂(C₆H₄Cl)N₂)2)}⁽¹⁺⁾*ClO₄^(1-)={RuCl(P(CH₃)3)2(C₅H₃N(C₃H₂(C₆H₄Cl)N₂)2)}ClO₄

Chemical Property:

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Safty Information:

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Useful:

Technology Process of {RuCl(P(CH₃)3)2(C₅H₃N(C₃H₂(C₆H₄Cl)N₂)2)}⁽¹⁺⁾*ClO₄^(1-)={RuCl(P(CH₃)3)2(C₅H₃N(C₃H₂(C₆H₄Cl)N₂)2)}ClO₄

There total 1 articles about {RuCl(P(CH₃)3)2(C₅H₃N(C₃H₂(C₆H₄Cl)N₂)2)}⁽¹⁺⁾*ClO₄^(1-)={RuCl(P(CH₃)3)2(C₅H₃N(C₃H₂(C₆H₄Cl)N₂)2)}ClO₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

RuCl3(C5H3N(C3H2(C6H4Cl)N2)2) (150414-08-7) + trimethylphosphane (594-09-2) → {RuCl(P(CH3)3)2(C5H3N(C3H2(C6H4Cl)N2)2)}(1+)*ClO4(1-)={RuCl(P(CH3)3)2(C5H3N(C3H2(C6H4Cl)N2)2)}ClO4 (150414-17-8)

Guidance literature:

With zinc amalgam; NaClO₄; In dichloromethane; Irradiation (UV/VIS); addn. of 4.5-7 equivs. of P(CH3)3 to the Ru(III) complex in CH2Cl2; addn. of Zn/Hg amalgam; refluxing for 24 h; irradiation (120 W) for several days; filtration; evapn. to dryness; dissolving in ethanol/H2O and addn. of solid NaClO4; performed under N2;; the ppt. was vac. filtered and washed with a minimum amt. of H2O; chromy. (Al2O3, acetone); evapn. to dryness; dissolving in acetone; the soln. was titurated into O(C2H5)2; the ppt. was washed with O(C2H5)2 and dried in air; elem. anal.;;

DOI:10.1039/DT9930001563

Reference yield:

{RuCl(P(CH3)3)2(C5H3N(C3H2(C6H4Cl)N2)2)}(1+)*ClO4(1-)={RuCl(P(CH3)3)2(C5H3N(C3H2(C6H4Cl)N2)2)}ClO4 (150414-17-8) → {Ru(NO2)(P(CH3)3)2(C5H3N(C3H2(C6H4Cl)N2)2)}(1+)*ClO4(1-)={Ru(NO2)(P(CH3)3)2(C5H3N(C3H2(C6H4Cl)N2)2)}ClO4

Guidance literature:

With NaNO₂; NaClO₄; In ethanol; water; addn. of solid NaNO2 (20 equivs.) to a soln. of the Ru(II) complex in 95% ethanol/H2O (50/50); refluxing for 1-3 h; concn.; addn. of solid NaClO4; performed under N2;; the ppt. was filtered off, washed with diethyl ether, and dried in air; chromy. (Al2O3, acetone); the eluate was concd. and titurated into toluene; elem. anal.;;

DOI:10.1039/DT9930001563

upstream raw materials:

RuCl₃(C₅H₃N(C₃H₂(C₆H₄Cl)N₂)2)

trimethylphosphane

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