4-benzyl-1,1,4-trimethyl-1,2-azaborolidine

Base Information

• Chemical Name: 4-benzyl-1,1,4-trimethyl-1,2-azaborolidine
• CAS No.: 1350465-79-0
• Molecular Formula: C₁₃H₂₂BN
• Molecular Weight: 203.135

Synonyms:

Chemical Property of 4-benzyl-1,1,4-trimethyl-1,2-azaborolidine

Chemical Property:

Purity/Quality:

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Technology Process of 4-benzyl-1,1,4-trimethyl-1,2-azaborolidine

There total 4 articles about 4-benzyl-1,1,4-trimethyl-1,2-azaborolidine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C6H5CH2C(CH3)2CH2N(CH3)2BH3 (1350465-78-9) → 1,1,4,4-tetramethyl-3-phenyl-1,2-azaborolidine (1350465-82-5) + 4-benzyl-1,1,4-trimethyl-1,2-azaborolidine (1350465-79-0) + C6H4(CH2)3BHN(CH3)2CCH3 (1350465-80-3)

Guidance literature:

C₆H₅CH₂C(CH₃)2CH₂N(CH₃)2BH₃; With bis(trifluoromethanesulfonyl)amide; In toluene; at 160 ℃; for 14h; Sealed tube;

With tetrabutylammonium borohydride; In toluene;

DOI:10.1021/ja208093c

Reference yield:

N,N,2-trimethylpropionamide (21678-37-5) → 1,1,4,4-tetramethyl-3-phenyl-1,2-azaborolidine (1350465-82-5) + 4-benzyl-1,1,4-trimethyl-1,2-azaborolidine (1350465-79-0) + C6H4(CH2)3BHN(CH3)2CCH3 (1350465-80-3)

Guidance literature:

Multi-step reaction with 3 steps

1.1: lithium diisopropyl amide / tetrahydrofuran / 2 h / -30 - 0 °C

1.2: -50 - 20 °C

2.1: dimethylsulfide borane complex / tetrahydrofuran / 20 °C / Inert atmosphere; Reflux

3.1: bis(trifluoromethanesulfonyl)amide / toluene / 14 h / 160 °C / Sealed tube

With dimethylsulfide borane complex; bis(trifluoromethanesulfonyl)amide; lithium diisopropyl amide; In tetrahydrofuran; toluene;

DOI:10.1021/ja208093c

Reference yield:

N,N,2,2-tetramethyl-3-phenylpropanamide (16487-55-1) → 1,1,4,4-tetramethyl-3-phenyl-1,2-azaborolidine (1350465-82-5) + 4-benzyl-1,1,4-trimethyl-1,2-azaborolidine (1350465-79-0) + C6H4(CH2)3BHN(CH3)2CCH3 (1350465-80-3)

Guidance literature:

Multi-step reaction with 2 steps

1: dimethylsulfide borane complex / tetrahydrofuran / 20 °C / Inert atmosphere; Reflux

2: bis(trifluoromethanesulfonyl)amide / toluene / 14 h / 160 °C / Sealed tube

With dimethylsulfide borane complex; bis(trifluoromethanesulfonyl)amide; In tetrahydrofuran; toluene;

DOI:10.1021/ja208093c

upstream raw materials:

C₆H₅CH₂C(CH₃)2CH₂N(CH₃)2BH₃

N,N,2-trimethylpropionamide

N,N,2,2-tetramethyl-3-phenylpropanamide

benzyl bromide

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