C₂₅H₄₂N₅O₉P

Base Information

• Chemical Name: C₂₅H₄₂N₅O₉P
• CAS No.: 1422188-81-5
• Molecular Formula: C₂₅H₄₂N₅O₉P
• Molecular Weight: 587.61
• Mol file: 1422188-81-5.mol

Synonyms:

Chemical Property of C₂₅H₄₂N₅O₉P

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₅H₄₂N₅O₉P

There total 6 articles about C₂₅H₄₂N₅O₉P which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C37H66N5O9P → C25H42N5O9P (1422188-81-5)

Guidance literature:

With trifluoroacetic acid; In dichloromethane; at 0 - 20 ℃; for 16h;

DOI:10.1039/c2ob26555a

Reference yield:

1-(1-[carbo-(1,1-dimethyl)ethoxy]-3-[4-nitrophenyl]propyl)-4,10-bis(carbo-[1,1-dimethyl]ethoxymethyl)-1,4,7,10-tetraazacyclododecane → C25H42N5O9P (1422188-81-5)

Guidance literature:

Multi-step reaction with 4 steps

1: potassium carbonate; potassium iodide / acetonitrile / 16 h / 20 - 70 °C

2: palladium 10% on activated carbon; hydrogen / ethanol / 1810.07 Torr

3: trimethylsilyl bromide / dichloromethane / 16 h / 0 - 20 °C

4: trifluoroacetic acid / dichloromethane / 16 h / 0 - 20 °C

With trimethylsilyl bromide; palladium 10% on activated carbon; hydrogen; potassium carbonate; trifluoroacetic acid; potassium iodide; In ethanol; dichloromethane; acetonitrile;

DOI:10.1039/c2ob26555a

Reference yield:

C41H72N5O11P (1422188-76-8) → C25H42N5O9P (1422188-81-5)

Guidance literature:

Multi-step reaction with 3 steps

1: palladium 10% on activated carbon; hydrogen / ethanol / 1810.07 Torr

2: trimethylsilyl bromide / dichloromethane / 16 h / 0 - 20 °C

3: trifluoroacetic acid / dichloromethane / 16 h / 0 - 20 °C

With trimethylsilyl bromide; palladium 10% on activated carbon; hydrogen; trifluoroacetic acid; In ethanol; dichloromethane;

DOI:10.1039/c2ob26555a

upstream raw materials:

C₄₁H₇₂N₅O₁₁P

C₄₁H₇₄N₅O₉P

4-(4-nitrophenyl)butanoic acid

(1,1-dimethyl)ethyl 2-bromo-4-(4-nitrophenyl)butanoate