[(1,8-(C6H4(Ph)P=N(p-isopropylphenyl))2-3,6-dimethylcarbazolide-κ3N)Lu(THF)]

Base Information

• Chemical Name: [(1,8-(C6H4(Ph)P=N(p-isopropylphenyl))2-3,6-dimethylcarbazolide-κ3N)Lu(THF)]
• CAS No.: 1194952-85-6
• Molecular Formula: C₆₀H₅₈LuN₃OP₂
• Molecular Weight: 1074.05

Synonyms:

Chemical Property of [(1,8-(C6H4(Ph)P=N(p-isopropylphenyl))2-3,6-dimethylcarbazolide-κ3N)Lu(THF)]

Chemical Property:

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Technology Process of [(1,8-(C6H4(Ph)P=N(p-isopropylphenyl))2-3,6-dimethylcarbazolide-κ3N)Lu(THF)]

There total 3 articles about [(1,8-(C6H4(Ph)P=N(p-isopropylphenyl))2-3,6-dimethylcarbazolide-κ3N)Lu(THF)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.5%

Lu(trimethylsilylmethyl)3(tetrahydrofuran)2 + HN(C6H2(CH3)P(C6H5)2NC6H4CH(CH3)2)2 (1194952-81-2) → [(1,8-(C6H4(Ph)P=N(p-isopropylphenyl))2-3,6-dimethylcarbazolide-κ3N)Lu(THF)] (1194952-85-6)

Guidance literature:

In benzene; byproducts: SiMe4; (Ar); glovebox; C6H6 was added to mixt. of ligand and Lu complex at ambient temp.; stirred for 18 h; THF added; layered with pentane; kept at ambient temp. over 48 h; filtered; washed (pentane); dried (vac.); elem. anal.;

DOI:10.1021/om900731x

Reference yield:

[(N(C6H2(CH3)P(C6H5)2NC6H4CH(CH3)2)2)Lu(CH2Si(CH3)3)2] (1194952-83-4) → [(1,8-(C6H4(Ph)P=N(p-isopropylphenyl))2-3,6-dimethylcarbazolide-κ3N)Lu(THF)] (1194952-85-6)

Guidance literature:

In ⁽²⁾H₈-toluene; (Ar); glovebox; C7D8 was added to mixt. of ligand and Lu complex in NMR tube at -78°C; briefly shaken; warmed to 295.7 K; NMR monitoring; Kinetics;

DOI:10.1021/om900731x

Reference yield:

HN(C6H2(CH3)P(C6H5)2NC6H4CH(CH3)2)2 (1194952-81-2) → [(1,8-(C6H4(Ph)P=N(p-isopropylphenyl))2-3,6-dimethylcarbazolide-κ3N)Lu(THF)] (1194952-85-6)

Guidance literature:

Multi-step reaction with 2 steps

1: ⁽²⁾H₈-toluene

2: ⁽²⁾H₈-toluene

In ⁽²⁾H₈-toluene;

DOI:10.1021/om900731x

upstream raw materials:

HN(C₆H₂(CH₃)P(C₆H₅)2NC₆H₄CH(CH₃)2)2

[(N(C₆H₂(CH₃)P(C₆H₅)2NC₆H₄CH(CH₃)2)2)Lu(CH₂Si(CH₃)3)2]

Downstream raw materials:

[(1,8-(Ph2P=N(p-isopropylphenyl))2-3,6-dimethylcarbazolide-κ3N,κC)Lu(NH-2,4,6-(t-Bu)3C6H2)]

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