(η6-2,4,6-trimethylpyridine)tricarbonylchromium(II)

Base Information

• Chemical Name: (η6-2,4,6-trimethylpyridine)tricarbonylchromium(II)
• CAS No.: 55853-04-8
• Molecular Formula: C₁₁H₁₁CrNO₃
• Molecular Weight: 257.209
• Mol file: 55853-04-8.mol

Synonyms:

Chemical Property of (η6-2,4,6-trimethylpyridine)tricarbonylchromium(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (η6-2,4,6-trimethylpyridine)tricarbonylchromium(II)

There total 1 articles about (η6-2,4,6-trimethylpyridine)tricarbonylchromium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,4,6-trimethyl-pyridine (108-75-8) + (CH3CN)3Cr(CO)3 (16800-46-7,22736-49-8) → (η6-2,4,6-trimethylpyridine)tricarbonylchromium(II) (55853-04-8,90541-13-2) + acetonitrile (75-05-8,26809-02-9)

Guidance literature:

In 1,4-dioxane; Cr complex and trimethylpyridine stirred in dioxane soln. for 14 h at 60°C, liberated CH3CN removed periodically by evacuation;

DOI:10.1016/S0022-328X(00)98560-7

Reference yield:

2,6-dimethylpyridine (108-48-5) + (η6-2,4,6-trimethylpyridine)tricarbonylchromium(II) (55853-04-8,90541-13-2) → 2,4,6-trimethyl-pyridine (108-75-8) + (η(6)-2,6-(CH3)2C5H3N)Cr(CO)3 (59391-49-0)

Guidance literature:

In further solvent(s); warming Cr complex in 2,6-dimethylpyridine;

DOI:10.1016/S0022-328X(00)98560-7

Reference yield:

(η6-2,4,6-trimethylpyridine)tricarbonylchromium(II) (55853-04-8,90541-13-2) → trans-bis(triphenylphosphine)chromium(0) tetracarbonyl (38800-75-8,42029-71-0,77551-77-0) + (η6-2,4,6-trimethylpyridine)-(triphenylphosphine)dicarbonylchromium(III) (85412-93-7)

Guidance literature:

With triphenylphosphine; In methyl cyclohexane; Irradiation (UV/VIS); irradn. of methylcyclohexane soln. of Cr complex in presence of PPh3;

DOI:10.1016/S0022-328X(00)98560-7

upstream raw materials:

2,4,6-trimethyl-pyridine

(CH₃CN)3Cr(CO)3

Downstream raw materials:

2,4,6-trimethyl-pyridine

(η(6)-2,6-(CH3)2C5H3N)Cr(CO)3

trans-bis(triphenylphosphine)chromium(0) tetracarbonyl

(η6-2,4,6-trimethylpyridine)-(triphenylphosphine)dicarbonylchromium(III)