methyl-{2-[6-(8-oxo-8H-furo[3',4':3,4]benzo[1,2-d][1,3]dioxol-6-ylidenemethyl)-benzo[1,3]dioxol-5-yl]-ethyl}-carbamic acid phenyl ester

Base Information

• Chemical Name: methyl-{2-[6-(8-oxo-8H-furo[3',4':3,4]benzo[1,2-d][1,3]dioxol-6-ylidenemethyl)-benzo[1,3]dioxol-5-yl]-ethyl}-carbamic acid phenyl ester
• CAS No.: 35321-06-3
• Molecular Formula: C₂₇H₂₁NO₈
• Molecular Weight: 487.466
• Mol file: 35321-06-3.mol

Synonyms:

Chemical Property of methyl-{2-[6-(8-oxo-8H-furo[3',4':3,4]benzo[1,2-d][1,3]dioxol-6-ylidenemethyl)-benzo[1,3]dioxol-5-yl]-ethyl}-carbamic acid phenyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl-{2-[6-(8-oxo-8H-furo[3',4':3,4]benzo[1,2-d][1,3]dioxol-6-ylidenemethyl)-benzo[1,3]dioxol-5-yl]-ethyl}-carbamic acid phenyl ester

There total 2 articles about methyl-{2-[6-(8-oxo-8H-furo[3',4':3,4]benzo[1,2-d][1,3]dioxol-6-ylidenemethyl)-benzo[1,3]dioxol-5-yl]-ethyl}-carbamic acid phenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ methyl-{2-[6-(8-oxo-8H-furo[3',4':3,4]benzo[1,2-d][1,3]dioxol-6-ylidenemethyl)-benzo[1,3]dioxol-5-yl]-ethyl}-carbamic acid phenyl ester (35321-06-3)

Guidance literature:

Aus Verb.1 u. Chlorameisensaeurephenylester;

DOI:10.1002/hlca.19710540736

Reference yield:

→ Methyl-(2-{6-[8-oxo-8H-furo[3',4':3,4]benzo[1,2-d][1,3]dioxol-(6Z)-ylidenemethyl]-benzo[1,3]dioxol-5-yl}-ethyl)-carbamic acid phenyl ester (35321-06-3)

Guidance literature:

aus (-)-Bicucullin (1a), Phenylchloroformat;

DOI:10.1002/hlca.19720550644

Reference yield:

methyl-{2-[6-(8-oxo-8H-furo[3',4':3,4]benzo[1,2-d][1,3]dioxol-6-ylidenemethyl)-benzo[1,3]dioxol-5-yl]-ethyl}-carbamic acid phenyl ester (35321-06-3) → rhoeadine (2718-25-4)

Guidance literature:

Multi-step reaction with 4 steps

1: aq. NaOH

2: (i) AcOH, (ii) air

3: (i) LiBH₄, THF, (ii) AcOH

4: (i) sodium bis-(2-methoxy-ethoxy)-aluminium hydride, Py, (ii) /BRN= 969215/, MeOH, H⁺

With sodium hydroxide;

DOI:10.1002/hlca.19710540736

Downstream raw materials:

rhoeadine