C₆₁H₉₄ClIO₁₁Si₂

Base Information

• Chemical Name: C₆₁H₉₄ClIO₁₁Si₂
• CAS No.: 1439788-98-3
• Molecular Formula: C₆₁H₉₄ClIO₁₁Si₂
• Molecular Weight: 1221.94
• Mol file: 1439788-98-3.mol

Synonyms:

Chemical Property of C₆₁H₉₄ClIO₁₁Si₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₆₁H₉₄ClIO₁₁Si₂

There total 22 articles about C₆₁H₉₄ClIO₁₁Si₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

diiodomethane (75-11-6) + C60H92ClIO12Si2 (1439788-90-5) → C61H94ClIO11Si2 (1439788-98-3)

Guidance literature:

diiodomethane; With chloro-trimethyl-silane; lead(II) iodide; zinc; at 0 - 20 ℃;

With titanium tetrachloride; In dichloromethane; at 20 ℃;

C₆₀H₉₂ClIO₁₂Si₂; In tetrahydrofuran; at 20 ℃;

DOI:10.1039/c3sc50304f

Reference yield:

C17H28O6 → C61H94ClIO11Si2 (1439788-98-3)

Guidance literature:

Multi-step reaction with 14 steps

1.1: MP-TsOH / ethanol; water / 82 °C

2.1: zinc trifluoromethanesulfonate / ethanol / 100 °C / Schlenk technique

3.1: methyl p-toluene sulfonate / toluene / 40 °C

4.1: lithium hydroxide monohydrate / tetrahydrofuran; water / 20 °C

5.1: benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine / tetrahydrofuran / 20 °C

6.1: osmium(VIII) oxide; 4-methylmorpholine N-oxide / acetone; water / 20 °C

7.1: lead(IV) tetraacetate / toluene / 20 °C

8.1: triethylamine; dicyclohexylboron chloride / diethyl ether / 2 h / 0 °C

8.2: 2 h / -78 °C

9.1: pyridinium p-toluenesulfonate / methanol / 20 °C

10.1: 2,6-dimethylpyridine / tetrahydrofuran / -78 °C

11.1: cerium(III) chloride / -78 °C

12.1: triethylamine; dicyclohexylboron chloride / diethyl ether / -55 °C

12.2: -70 °C

13.1: 1H-imidazole / N,N-dimethyl-formamide / 20 °C

14.1: zinc; lead(II) iodide; chloro-trimethyl-silane / 0 - 20 °C

14.2: 20 °C

14.3: 20 °C

With 1H-imidazole; 2,6-dimethylpyridine; osmium(VIII) oxide; chloro-trimethyl-silane; cerium(III) chloride; lithium hydroxide monohydrate; dicyclohexylboron chloride; lead(IV) tetraacetate; pyridinium p-toluenesulfonate; zinc trifluoromethanesulfonate; benzotriazol-1-ol; 4-methylmorpholine N-oxide; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine; methyl p-toluene sulfonate; lead(II) iodide; zinc; In tetrahydrofuran; methanol; diethyl ether; ethanol; water; N,N-dimethyl-formamide; acetone; toluene;

DOI:10.1039/c3sc50304f

Reference yield:

C14H24O6 → C61H94ClIO11Si2 (1439788-98-3)

Guidance literature:

Multi-step reaction with 13 steps

1.1: zinc trifluoromethanesulfonate / ethanol / 100 °C / Schlenk technique

2.1: methyl p-toluene sulfonate / toluene / 40 °C

3.1: lithium hydroxide monohydrate / tetrahydrofuran; water / 20 °C

4.1: benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine / tetrahydrofuran / 20 °C

5.1: osmium(VIII) oxide; 4-methylmorpholine N-oxide / acetone; water / 20 °C

6.1: lead(IV) tetraacetate / toluene / 20 °C

7.1: triethylamine; dicyclohexylboron chloride / diethyl ether / 2 h / 0 °C

7.2: 2 h / -78 °C

8.1: pyridinium p-toluenesulfonate / methanol / 20 °C

9.1: 2,6-dimethylpyridine / tetrahydrofuran / -78 °C

10.1: cerium(III) chloride / -78 °C

11.1: triethylamine; dicyclohexylboron chloride / diethyl ether / -55 °C

11.2: -70 °C

12.1: 1H-imidazole / N,N-dimethyl-formamide / 20 °C

13.1: zinc; lead(II) iodide; chloro-trimethyl-silane / 0 - 20 °C

13.2: 20 °C

13.3: 20 °C

With 1H-imidazole; 2,6-dimethylpyridine; osmium(VIII) oxide; chloro-trimethyl-silane; cerium(III) chloride; lithium hydroxide monohydrate; dicyclohexylboron chloride; lead(IV) tetraacetate; pyridinium p-toluenesulfonate; zinc trifluoromethanesulfonate; benzotriazol-1-ol; 4-methylmorpholine N-oxide; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine; methyl p-toluene sulfonate; lead(II) iodide; zinc; In tetrahydrofuran; methanol; diethyl ether; ethanol; water; N,N-dimethyl-formamide; acetone; toluene;

DOI:10.1039/c3sc50304f

upstream raw materials:

C₁₄H₂₄O₆

C₃₈H₄₈O₉

2-{(2R,3R,4R,5R,6R)-3,4-Bis-(4-methoxy-benzyloxy)-6-[(S)-1-(4-methoxy-benzyloxy)-2-oxo-propyl]-5-methyl-tetrahydro-pyran-2-yl}-N-methoxy-N-methyl-acetamide

2-[(2R,3R,4R,5R,6R)-6-[(1S,4S,5R,6R)-10-Chloro-4-hydroxy-1-(4-methoxy-benzyloxy)-5-methyl-2-oxo-6-triethylsilanyloxy-decyl]-3,4-bis-(4-methoxy-benzyloxy)-5-methyl-tetrahydro-pyran-2-yl]-N-methoxy-N-methyl-acetamide

Downstream raw materials:

C₆₁H₉₄I₂O₁₁Si₂