2,5,8,9-Tetraaza-1-phosphabicyclo[3.3.3]undecane, 2,8,9-tris(phenylmethyl)-

Base Information

Chemical Name:2,5,8,9-Tetraaza-1-phosphabicyclo[3.3.3]undecane, 2,8,9-tris(phenylmethyl)-
CAS No.:130761-22-7
Molecular Formula:C27H33N4P
Molecular Weight:444.55100
Hs Code.:

Synonyms:2,8,9-tribenzyl-2,3,8,9-tetraaza-1-phosphabicyclo[3,3,3]undecane;2,8,9-Tribenzyl-2,5,8,9-tetraaza-1-phospha-bicyclo[3.3.3]undecane;P[-N(Bn)-CH2-CH2]3N;P[-N(Bn)-CH2-CH2-]3N;

Suppliers and Price of 2,5,8,9-Tetraaza-1-phosphabicyclo[3.3.3]undecane, 2,8,9-tris(phenylmethyl)-

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2,5,8,9-Tetraaza-1-phosphabicyclo[3.3.3]undecane, 2,8,9-tris(phenylmethyl)-

Chemical Property:

PSA：26.55000
LogP:4.80070

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 2,5,8,9-Tetraaza-1-phosphabicyclo[3.3.3]undecane, 2,8,9-tris(phenylmethyl)-

There total 5 articles about 2,5,8,9-Tetraaza-1-phosphabicyclo[3.3.3]undecane, 2,8,9-tris(phenylmethyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

: [HP(N(CH₂Ph)CH₂CH₂)3N]Cl

: 130761-22-7
2,8,9-tribenzyl-2,3,8,9-tetraaza-1-phosphabicyclo[3,3,3]undecane

Guidance literature:: With lithium hexamethyldisilazane; In tetrahydrofuran; pentane; at 25 ℃; for 22h; Inert atmosphere;
DOI:10.1021/jo901571y

Reference yield:

: 2,8,9-tribenzyl-2,5,8,9-tetraaza-1-phospha-bicyclo[3.3.3]undecane; hydrochloride

: 130761-22-7
2,8,9-tribenzyl-2,3,8,9-tetraaza-1-phosphabicyclo[3,3,3]undecane

Guidance literature:: With potassium tert-butylate; In dichloromethane; at 20 ℃; for 2h; Schlenk technique;
DOI:10.1021/acs.inorgchem.1c01005

Reference yield:

: 122-78-1
phenylacetaldehyde

: 130761-22-7
2,8,9-tribenzyl-2,3,8,9-tetraaza-1-phosphabicyclo[3,3,3]undecane

Guidance literature:: Multi-step reaction with 3 steps

1.1: methanol / 2 h / 20 °C

1.2: 3 h / 0 - 20 °C

2.1: acetonitrile / 0 - 40 °C / Inert atmosphere

3.1: potassium tert-butylate / dichloromethane / 2 h / 20 °C / Schlenk technique

With potassium tert-butylate; In methanol; dichloromethane; acetonitrile;
DOI:10.1021/acs.inorgchem.1c01005