C₄₄H₆₈O₆Si₂

Base Information

• Chemical Name: C₄₄H₆₈O₆Si₂
• CAS No.: 1313218-91-5
• Molecular Formula: C₄₄H₆₈O₆Si₂
• Molecular Weight: 749.191
• Mol file: 1313218-91-5.mol

Synonyms:

Chemical Property of C₄₄H₆₈O₆Si₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₄₄H₆₈O₆Si₂

There total 6 articles about C₄₄H₆₈O₆Si₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C36H48O6Si (1313218-79-9) → C44H68O6Si2 (1313218-91-5)

Guidance literature:

Multi-step reaction with 6 steps

1: acetic acid; tetramethylammonium triacetoxyborohydride / acetonitrile / -15 °C

2: (+/-)-CSA / toluene / Reflux

3: 2,6-dimethylpyridine / dichloromethane

4: lithium diisopropyl amide / tetrahydrofuran / -78 °C

5: dichloro-R-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl ruthenium; hydrogen / ethanol / 35 - 40 °C / 58505.9 Torr

6: lithium borohydride / tetrahydrofuran

With 2,6-dimethylpyridine; lithium borohydride; dichloro-R-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl ruthenium; hydrogen; acetic acid; tetramethylammonium triacetoxyborohydride; lithium diisopropyl amide; In tetrahydrofuran; ethanol; dichloromethane; toluene; acetonitrile;

DOI:10.1073/pnas.1015270108

Reference yield:

C34H44O5Si (1310025-34-3) → C44H68O6Si2 (1313218-91-5)

Guidance literature:

Multi-step reaction with 4 steps

1: 2,6-dimethylpyridine / dichloromethane

2: lithium diisopropyl amide / tetrahydrofuran / -78 °C

3: dichloro-R-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl ruthenium; hydrogen / ethanol / 35 - 40 °C / 58505.9 Torr

4: lithium borohydride / tetrahydrofuran

With 2,6-dimethylpyridine; lithium borohydride; dichloro-R-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl ruthenium; hydrogen; lithium diisopropyl amide; In tetrahydrofuran; ethanol; dichloromethane;

DOI:10.1073/pnas.1015270108

Reference yield:

C36H50O6Si (1313218-80-2) → C44H68O6Si2 (1313218-91-5)

Guidance literature:

Multi-step reaction with 5 steps

1: (+/-)-CSA / toluene / Reflux

2: 2,6-dimethylpyridine / dichloromethane

3: lithium diisopropyl amide / tetrahydrofuran / -78 °C

4: dichloro-R-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl ruthenium; hydrogen / ethanol / 35 - 40 °C / 58505.9 Torr

5: lithium borohydride / tetrahydrofuran

With 2,6-dimethylpyridine; lithium borohydride; dichloro-R-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl ruthenium; hydrogen; lithium diisopropyl amide; In tetrahydrofuran; ethanol; dichloromethane; toluene;

DOI:10.1073/pnas.1015270108

upstream raw materials:

C₃₄H₄₄O₅Si

C₃₆H₄₈O₆Si

C₃₆H₅₀O₆Si

C₄₀H₅₈O₅Si₂

Downstream raw materials:

C₄₀H₆₄O₇Si₂

C₄₇H₇₂O₆Si₂