2-diphenylphosphino-[2-(diphenylphosphino)ferrocenyl]acetonitrile

Base Information

Chemical Name:2-diphenylphosphino-[2-(diphenylphosphino)ferrocenyl]acetonitrile
CAS No.:916769-21-6
Molecular Formula:C₃₆H₂₉FeNP₂
Molecular Weight:593.427
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Chemical Property of 2-diphenylphosphino-[2-(diphenylphosphino)ferrocenyl]acetonitrile

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Technology Process of 2-diphenylphosphino-[2-(diphenylphosphino)ferrocenyl]acetonitrile

There total 1 articles about 2-diphenylphosphino-[2-(diphenylphosphino)ferrocenyl]acetonitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: 525573-16-4
[2-(diphenylphosphino)ferrocenyl]acetonitrile

: 1070-89-9
sodium hexamethyldisilazane

: 1079-66-9,74391-44-9
chloro-diphenylphosphine

: 916769-21-6
2-diphenylphosphino-[2-(diphenylphosphino)ferrocenyl]acetonitrile

Guidance literature:: In tetrahydrofuran; to stirred soln. of 2-(diphenylposphino)-ferrocenyl acetonitrile in dry THF cooled to -78°C NaN(SiMe3)2 dissolved in THF added dropwise; mixt. stirred for 30 min.; (C6H5)PCl added at -78°C; stirred for 15 min, then at room temp. for 90 min; quenched with aq. NaCl soln.; org. phase separated; washed twice with satd. aq. NaCl; dried over MgSO4; pre-adsorbed onto silica gel by co-evaporation; purified by column chromy. (silica gel/hexane-ether 10:1); evaporation; single diastereomer as oil;
DOI:10.1016/j.inoche.2005.12.003