(2E,4E,6E,8E)-10-({(3R,4S,5S,6R)-5-methoxy-4-[2-methyl-3-(3-methylbut-2-en-1-yl)oxiran-2-yl]-1-oxaspiro[2.5]oct-6-yl}oxy)-10-oxodeca-2,4,6,8-tetraenoic acid

Base Information

• Chemical Name: (2E,4E,6E,8E)-10-({(3R,4S,5S,6R)-5-methoxy-4-[2-methyl-3-(3-methylbut-2-en-1-yl)oxiran-2-yl]-1-oxaspiro[2.5]oct-6-yl}oxy)-10-oxodeca-2,4,6,8-tetraenoic acid
• CAS No.: 297-95-0
• Molecular Formula: C₂₆H₃₄O₇
• Molecular Weight: 458.552

Synonyms:

Chemical Property of (2E,4E,6E,8E)-10-({(3R,4S,5S,6R)-5-methoxy-4-[2-methyl-3-(3-methylbut-2-en-1-yl)oxiran-2-yl]-1-oxaspiro[2.5]oct-6-yl}oxy)-10-oxodeca-2,4,6,8-tetraenoic acid

Chemical Property:

• Vapor Pressure: 2.7E-16mmHg at 25°C

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2E,4E,6E,8E)-10-({(3R,4S,5S,6R)-5-methoxy-4-[2-methyl-3-(3-methylbut-2-en-1-yl)oxiran-2-yl]-1-oxaspiro[2.5]oct-6-yl}oxy)-10-oxodeca-2,4,6,8-tetraenoic acid

There total 3 articles about (2E,4E,6E,8E)-10-({(3R,4S,5S,6R)-5-methoxy-4-[2-methyl-3-(3-methylbut-2-en-1-yl)oxiran-2-yl]-1-oxaspiro[2.5]oct-6-yl}oxy)-10-oxodeca-2,4,6,8-tetraenoic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

fumagillol (35903-52-7,128656-25-7,132746-73-7,108102-51-8) + (2E,4E,6E,8E)-Deca-2,4,6,8-tetraenedioyl dichloride → fumagillin (23110-15-8,297-95-0)

Guidance literature:

DOI:10.1021/ja990784k

Reference yield:

→ (3R,4S)-6t-(9t-carboxy-nona-2t,4t,6t,8-tetraenoyloxy)-4r-((1S,2Ξ)-1,2-epoxy-1,5-dimethyl-hex-4-enyl)-5t-methoxy-1-oxa-spiro[2.5]octane (23110-15-8,35903-50-5,297-95-0)

Guidance literature:

durch Synthese des Racemats;

DOI:10.1021/ja00762a080

Reference yield:

→ Fumagillin (856785-88-1,297-95-0)

Guidance literature:

Biosynthese aus Essigsaeure bezw. Mervalonsaeure in 'aspergillus fumigatus';

DOI:10.1039/j39690001473

upstream raw materials:

fumagillol

Downstream raw materials:

fumagillol

ligerin

1-chloromethyl-3-methoxy-2-[2-methyl-3-(3-methylbut-2-enyl)oxiranyl]cyclohexane-1,4-diol

7-bromo-6-(3-carboxy-1-oxopropyl)-fumagillol

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