[fac-Re(I)(CO)3(tris(4,4-dimethyl-2-oxazolinyl)phenylborate-κ3N,N',N'')]

Base Information

• Chemical Name: [fac-Re(I)(CO)3(tris(4,4-dimethyl-2-oxazolinyl)phenylborate-κ3N,N',N'')]
• CAS No.: 1335317-68-4
• Molecular Formula: C₂₄H₂₉BN₃O₆Re
• Molecular Weight: 652.529
• Mol file: 1335317-68-4.mol

Synonyms:

Chemical Property of [fac-Re(I)(CO)3(tris(4,4-dimethyl-2-oxazolinyl)phenylborate-κ3N,N',N'')]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [fac-Re(I)(CO)3(tris(4,4-dimethyl-2-oxazolinyl)phenylborate-κ3N,N',N'')]

There total 1 articles about [fac-Re(I)(CO)3(tris(4,4-dimethyl-2-oxazolinyl)phenylborate-κ3N,N',N'')] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

rhenium(I) pentacarbonyl bromide (14220-21-4) + lithium tris(4,4-dimethyl-2-oxazolinyl)phenylborate (1030839-74-7) → [fac-Re(I)(CO)3(tris(4,4-dimethyl-2-oxazolinyl)phenylborate-κ3N,N',N'')] (1335317-68-4)

Guidance literature:

In tetrahydrofuran; byproducts: LiBr, CO; (inert atm.); addn. of THF soln. of borate deriv. to suspn. of rhenium compd. in THF, heating at 80°C for 8 h; evapn., extn. (benzene), evapn., washing with pentane, drying in vac., elem. anal.;

DOI:10.1039/c1nj20222g

Reference yield:

[fac-Re(I)(CO)3(tris(4,4-dimethyl-2-oxazolinyl)phenylborate-κ3N,N',N'')] (1335317-68-4) → [fac-Re(II)(CO)3(tris(4,4-dimethyl-2-oxazolinyl)phenylborate-κ3N,N',N'')](1+) (1335317-80-0)

Guidance literature:

With (C₄H₉)4NB(C₆F₅)4; In dichloromethane; Electrolysis; (Ar, Schlenk technique); electrolysis of soln. of rhenium compd. in 0.05M soln. of tetrabutylammonium salt in dry CH2Cl2 at 253 K or 298 K; detected by IR;

DOI:10.1039/c1nj20222g

upstream raw materials:

rhenium(I) pentacarbonyl bromide

lithium tris(4,4-dimethyl-2-oxazolinyl)phenylborate

Downstream raw materials:

[fac-Re(II)(CO)3(tris(4,4-dimethyl-2-oxazolinyl)phenylborate-κ3N,N',N'')](1+)