[(η6-C6H5PMePh)Mo(bis(diphenylphosphinoethyl)phenylphosphine)]

Base Information

Chemical Name:[(η6-C6H5PMePh)Mo(bis(diphenylphosphinoethyl)phenylphosphine)]
CAS No.:1360642-09-6
Molecular Formula:C₄₇H₄₆MoP₄
Molecular Weight:830.717
Hs Code.:

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Chemical Property of [(η6-C6H5PMePh)Mo(bis(diphenylphosphinoethyl)phenylphosphine)]

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Technology Process of [(η6-C6H5PMePh)Mo(bis(diphenylphosphinoethyl)phenylphosphine)]

There total 3 articles about [(η6-C6H5PMePh)Mo(bis(diphenylphosphinoethyl)phenylphosphine)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

: 75365-56-9
trans-[Mo(N₂)2(bis(diphenylphosphinoethyl)phenylphosphine)(PMePh₂)]

: 1360642-09-6
[(η6-C6H5PMePh)Mo(bis(diphenylphosphinoethyl)phenylphosphine)]

Guidance literature:: In neat (no solvent, solid phase); byproducts: N2; (N2); Schlenk technique; Mo complex was heated at 60°C for 17 h;
DOI:10.1021/ic202430m

Reference yield: 48.0%

: 10241-05-1
molybdenum(V) chloride

: 23582-02-7
bis(2-diphenylphosphinoethyl)phenylphosphine

: 1360642-09-6
[(η6-C6H5PMePh)Mo(bis(diphenylphosphinoethyl)phenylphosphine)]

Guidance literature:: With Mg; In tetrahydrofuran; (N2); Schlenk technique; precooled (-78°C) soln. of PMePh2/THF (1.01 equiv.), activated Mg added to triphos (1 equiv.), MoCl5 (1 equiv.) cooled in acetone/dry ice bath; after 30 min bath removed; stirred (17 h); heated (60°C, 24 h); evapd. (vac.); extd. (toluene) in glovebox; filtered (Celite); evapd. (vac.); stirred in MeOH for 1 h; filtered; washing and filtration repeated2 times; dried (vac.);
DOI:10.1021/ic202430m

Reference yield: 4.0%

: 7727-37-9
nitrogen

: 10241-05-1
molybdenum(V) chloride

: 23582-02-7
bis(2-diphenylphosphinoethyl)phenylphosphine

: 75365-56-9
trans-[Mo(N₂)2(bis(diphenylphosphinoethyl)phenylphosphine)(PMePh₂)]

: 1360642-09-6
[(η6-C6H5PMePh)Mo(bis(diphenylphosphinoethyl)phenylphosphine)]

Guidance literature:: With Mg; In tetrahydrofuran; (N2); Schlenk technique; precooled (-78°C) soln. of PMePh2/THF (1.07 equiv.), activated Mg were sequentially added to mixt. of triphos (1.01 equiv.), MoCl5 (1 equiv.) cooled in acetone/dry ice bath; after 30 min bath was removed; stirred (17 h); evapd. (vac.); extd. (toluene) in glovebox; filtered (Celite); evapd. (vac.); redissolved in THF; layered with MeOH; kept (-30°C, 2 d); redissolved in THF; layered with MeOH; kept (-30°C, 3 d); filtered; washed (MeOH); dried (vac.);
DOI:10.1021/ic202430m