tri-p-tolylantimony(V)bis((μ-oxo)diphenylarsenic(III))

Base Information

• Chemical Name: tri-p-tolylantimony(V)bis((μ-oxo)diphenylarsenic(III))
• CAS No.: 221132-60-1
• Molecular Formula: C₄₅H₄₁As₂O₂Sb
• Molecular Weight: 885.413
• Mol file: 221132-60-1.mol

Synonyms:

Chemical Property of tri-p-tolylantimony(V)bis((μ-oxo)diphenylarsenic(III))

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of tri-p-tolylantimony(V)bis((μ-oxo)diphenylarsenic(III))

There total 1 articles about tri-p-tolylantimony(V)bis((μ-oxo)diphenylarsenic(III)) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

triphenyl-arsane (603-32-7) + tri(p-tolyl)antimony dibromide (60043-16-5) → tri-p-tolylantimony(V)bis((μ-oxo)diphenylarsenic(III)) (221132-60-1)

Guidance literature:

With Li; air; t-BuCl; In tetrahydrofuran; byproducts: LiBr, C6H6, isobutene; dry N2-atmosphere; treatment of AsPh3 with Li, addn. of t-BuCl, dropwise addn. of stoich. amt. of Sb-compd., stirring for 30 min; solvent removal (vac.), extn. into C6H6 (in air), filtration, concn., crystn. on hexane addn., recrystn. (CHCl3/hexane=1:1), drying (vac.); elem. anal.;

DOI:10.1016/S0022-328X(98)00908-5

upstream raw materials:

triphenyl-arsane

tri(p-tolyl)antimony dibromide