Ni(C₆H₅CCC₆H₅)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)

Base Information

Chemical Name:Ni(C₆H₅CCC₆H₅)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)
CAS No.:97921-17-0
Molecular Formula:C₄₀H₅₈NiP₂
Molecular Weight:659.538
Hs Code.:

Ni(C<sub>6</sub>H<sub>5</sub>CCC<sub>6</sub>H<sub>5</sub>)((C<sub>6</sub>H<sub>11</sub>)2PCH<sub>2</sub>CH<sub>2</sub>P(C<sub>6</sub>H<sub>11</sub>)2)

Synonyms:

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Chemical Property of Ni(C₆H₅CCC₆H₅)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)

Chemical Property:

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Technology Process of Ni(C₆H₅CCC₆H₅)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)

There total 4 articles about Ni(C₆H₅CCC₆H₅)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: 91513-98-3
Ni(η(2)-C2H4)(1,2-bis(dicyclohexylphosphino)ethane)

: 501-65-5
diphenyl acetylene

: 97921-17-0
Ni(C₆H₅CCC₆H₅)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)

Guidance literature:: In benzene; benzene was added to mixt. of Ni-complex and Ph2C2 under N2, stirred for 5 min; soln. was concd., dild. with pentane, resulting crystals were recrystd.from hot toluene by addn. of hexane and dried in vacuo at 80°C for 3 h; elem. anal.;

Reference yield: 60.0%

: 114907-51-6
[η²-benzyne][1,2-bis(dicyclohexylphosphino)ethane]nickel(0)

: 501-65-5
diphenyl acetylene

: 97921-17-0
Ni(C₆H₅CCC₆H₅)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)

: Ni(C(C₆H₅)C(C₆H₅)C₆H₄)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)

Guidance literature:: In benzene; soln. of Ni-complex and Ph2C2 in benzene was heated under N2 at 80°C for 7.5 h; attempts to induce insertion of Ph2C2 into the Ni-benzyne bond of the starting complex at higher temps. led only to hexaphenylbenzene; concd., dild. with pentane, alternately cooled in liq. N2 and allowed to warm until crystals formed, more pentane was added, ppt. dissolved in benzene, dild. with pentane, filtered, addn. of pentane gave ppt. of theproduct; identified by IR and NMR;

Reference yield:

: 96555-88-3
[(1,2-bis(dicyclohexylphosphino)ethane)dichloronickel(II)]

: 97921-17-0
Ni(C₆H₅CCC₆H₅)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)

Guidance literature:: Multi-step reaction with 2 steps

1: lithium / tetrahydrofuran

2: benzene

With lithium; In tetrahydrofuran; benzene;