[trans-P-Rh-B-Rh(CNt-Bu)(PPh₃)(B(methimazolyl)3)]Cl

Base Information

• Chemical Name: [trans-P-Rh-B-Rh(CNt-Bu)(PPh₃)(B(methimazolyl)3)]Cl
• CAS No.: 874200-63-2
• Molecular Formula: C₃₅H₃₉BN₇PRhS₃*Cl
• Molecular Weight: 834.083
• Mol file: 874200-63-2.mol

Synonyms:

Chemical Property of [trans-P-Rh-B-Rh(CNt-Bu)(PPh₃)(B(methimazolyl)3)]Cl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [trans-P-Rh-B-Rh(CNt-Bu)(PPh₃)(B(methimazolyl)3)]Cl

There total 1 articles about [trans-P-Rh-B-Rh(CNt-Bu)(PPh₃)(B(methimazolyl)3)]Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

[1,2:5,6-η-(1,5-cycloodiene)]triphenylphosphinechlororuthenium (31781-57-4) + tert-butylisonitrile (119072-55-8,7188-38-7) + sodium tris(2-mercapto-1-methylimidazolyl)borate → [trans-P-Rh-B-Rh(CNt-Bu)(PPh3)(B(methimazolyl)3)]Cl (874200-63-2)

Guidance literature:

In ethanol; dichloromethane; a mixt. of complexes in CH2Cl2 and ethanol was stirred anaerobically for1 h, filtered, an excess of CNC(CH3)3 was added, stirred for 12 h; concd. under reduced pressure, an excess of diethyl ether was added, filtered, dried in vac., recrystd. from CH2Cl2-diethyl ether; elem. anal.;

DOI:10.1021/om050772+

upstream raw materials:

[1,2:5,6-η-(1,5-cycloodiene)]triphenylphosphinechlororuthenium

tert-butylisonitrile