allyl O--(1->6)-<2-<(3R)-3-acetoxytetradecanamido>-3-O-benzoyl-2-deoxy-β-D-glucopyranoside 4->

Base Information

Chemical Name:allyl O--(1->6)-<2-<(3R)-3-acetoxytetradecanamido>-3-O-benzoyl-2-deoxy-β-D-glucopyranoside 4->
CAS No.:142141-02-4
Molecular Formula:C₅₃H₇₄Cl₆NO₂₃P
Molecular Weight:1336.86
Hs Code.:

allyl O-<methyl(4,5,7,8-tetra-O-acetyl-α-D-manno-oct-2-ulopyranos)onic acid>-(1->6)-<2-<(3R)-3-acetoxytetradecanamido>-3-O-benzoyl-2-deoxy-β-D-glucopyranoside 4-<bis(trichloroethyl) phosphate>>

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Suppliers and Price of allyl O--(1->6)-<2-<(3R)-3-acetoxytetradecanamido>-3-O-benzoyl-2-deoxy-β-D-glucopyranoside 4->

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of allyl O--(1->6)-<2-<(3R)-3-acetoxytetradecanamido>-3-O-benzoyl-2-deoxy-β-D-glucopyranoside 4->

Chemical Property:

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Technology Process of allyl O--(1->6)-<2-<(3R)-3-acetoxytetradecanamido>-3-O-benzoyl-2-deoxy-β-D-glucopyranoside 4->

There total 14 articles about allyl O--(1->6)-<2-<(3R)-3-acetoxytetradecanamido>-3-O-benzoyl-2-deoxy-β-D-glucopyranoside 4-> which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 18.0%

: 17672-53-6
bis-(2,2,2-trichloroethyl)phosphorochloridate

: 142141-01-3,142187-27-7
allyl O--(1->6)-2-<(3R)-3-acetoxytetradecanamido>-3-O-benzoyl-2-deoxy-β-D-glucopyranoside

: 142141-02-4,142187-28-8
allyl O--(1->6)-<2-<(3R)-3-acetoxytetradecanamido>-3-O-benzoyl-2-deoxy-β-D-glucopyranoside 4->

: 142141-02-4,142187-28-8
allyl O--(1->6)-<2-<(3R)-3-acetoxytetradecanamido>-3-O-benzoyl-2-deoxy-β-D-glucopyranoside 4->

Guidance literature:: With 1-methyl-1H-imidazole; In tetrahydrofuran; at 60 ℃;
DOI:10.1016/S0008-6215(00)90547-0

Reference yield: 18.0%

: 17672-53-6
bis-(2,2,2-trichloroethyl)phosphorochloridate

: 142141-01-3,142187-27-7
allyl O--(1->6)-2-<(3R)-3-acetoxytetradecanamido>-3-O-benzoyl-2-deoxy-β-D-glucopyranoside

: 142141-02-4,142187-28-8
allyl O--(1->6)-<2-<(3R)-3-acetoxytetradecanamido>-3-O-benzoyl-2-deoxy-β-D-glucopyranoside 4->

: 142141-02-4,142187-28-8
allyl O--(1->6)-<2-<(3R)-3-acetoxytetradecanamido>-3-O-benzoyl-2-deoxy-β-D-glucopyranoside 4->

Guidance literature:: With 1-methyl-1H-imidazole; In tetrahydrofuran; at 60 ℃;
DOI:10.1016/S0008-6215(00)90547-0

Reference yield:

: 63064-48-2,116288-58-5,117299-90-8,126778-02-7,28738-44-5
allyl 2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranoside

: 142141-02-4,142187-28-8
allyl O--(1->6)-<2-<(3R)-3-acetoxytetradecanamido>-3-O-benzoyl-2-deoxy-β-D-glucopyranoside 4->

Guidance literature:: Multi-step reaction with 7 steps

1: 100 percent / Ba(OH)2*8H₂O / H₂O / 110 °C

2: 87 percent / methanol / 48 h / Ambient temperature

3: 81 percent / 4-toluenesulphonic acid / tetrahydrofuran; acetonitrile / 1 h / Ambient temperature

4: 80 percent / 4-dimethylaminopyridine / pyridine / 30 °C

5: 94 percent / 1.5 M trifluoroacetic acid, silica gel / CH₂Cl₂ / 4 h / Ambient temperature

6: 65 percent / Hg(CN)2, MS 4A / acetonitrile / 0.25 h

7: 31 percent / N-methylimidazole / tetrahydrofuran / 60 °C

With 1-methyl-1H-imidazole; dmap; barium dihydroxide; mercury(II) cyanide; silica gel; toluene-4-sulfonic acid; trifluoroacetic acid; In tetrahydrofuran; pyridine; methanol; dichloromethane; water; acetonitrile;
DOI:10.1016/S0008-6215(00)90547-0