cis-2-ethylcyclohexanol

Base Information

• Chemical Name: cis-2-ethylcyclohexanol
• CAS No.: 116697-35-9
• Molecular Formula: C₈H₁₆O
• Molecular Weight: 128.214
• Mol file: 116697-35-9.mol

Synonyms:

Chemical Property of cis-2-ethylcyclohexanol

Chemical Property:

• Melting Point: 19.68°C (estimate)
• Refractive Index: 1.4655
• Boiling Point: 187.67°C (estimate)
• Density: 0.9274

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-2-ethylcyclohexanol

There total 15 articles about cis-2-ethylcyclohexanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

2-Ethyl-1-hexen oxide (223480-81-7) → 2-ethylcyclohexanol (3274-96-2,4276-43-1,69854-63-3,84275-94-5,89886-25-9,89886-26-0,95529-72-9,116697-35-9,3760-20-1)

Guidance literature:

With morpholine-borane; boron trifluoride diethyl etherate; In diethyl ether; for 2h; Product distribution; Ambient temperature;

DOI:10.1021/jo00191a036

Reference yield: 29.0%

2-ethylcyclohexanol (3274-96-2,4276-43-1,69854-63-3,84275-94-5,89886-25-9,89886-26-0,95529-72-9,116697-35-9,3760-20-1) → cis-2-ethylcyclohexanol (3760-20-1,4276-43-1,69854-63-3,84275-94-5,89886-25-9,89886-26-0,95529-72-9,116697-35-9,3274-96-2)

Guidance literature:

DOI:10.1139/v82-423

Reference yield:

2-ethyl-6-methoxyphenol (90534-46-6) → o-Hydroxyethylbenzene (90-00-6) + ethylbenzene (100-41-4,27536-89-6) + 2-ethylcyclohexanol (3274-96-2,4276-43-1,69854-63-3,84275-94-5,89886-25-9,89886-26-0,95529-72-9,116697-35-9,3760-20-1)

Guidance literature:

With hydrogen; In water; at 230 ℃; for 4h; under 7500.75 Torr; Autoclave;

DOI:10.1016/j.mcat.2017.12.009

upstream raw materials:

2-Ethyl-1-hexen oxide

o-Hydroxyethylbenzene

2-ethyl-2-cyclohexen-1-one

ethyl-cyclohexane

Downstream raw materials:

(+/-)-phenylcarbamic acid-(cis-2-ethyl-cyclohexyl ester)

(+/-)-naphthyl-⁽¹⁾-carbamic acid-(cis-2-ethyl-cyclohexyl ester)

2,4-Bis-(2-ethyl-cyclohexyloxy)-2,2,4,4-tetrafluoro-1,3-dimethyl-2λ⁵,4λ⁵-[1,3,2,4]diazadiphosphetidine

2-ethylcyclohexanone

Refernces

• 1、 Smith, William B.. "Ring Opening of Epoxides with Morpholine-Borane". . p. 3219 - 3220. Retrieved 1984.
• 2、 Hua, Manli,Song, Jinliang,Xie, Chao,Wu, Haoran,Hu, Yue,Huang, Xin,Han, Buxing. "Ru/hydroxyapatite as a dual-functional catalyst for efficient transfer hydrogenolytic cleavage of aromatic ether bonds without additional bases". supporting information. p. 5073 - 5079. Retrieved 2019/09/30.
• 3、 Cui, Xinjiang,Yuan, Hangkong,Junge, Kathrin,Topf, Christoph,Beller, Matthias,Shi, Feng. "A stable and practical nickel catalyst for the hydrogenolysis of C-O bonds". . p. 305 - 310. Retrieved 2017/01/24.