4-Methyl-1-decene

Base Information

• Chemical Name: 4-Methyl-1-decene
• CAS No.: 13151-29-6
• Molecular Formula: C11H22
• Molecular Weight: 154.296
• Hs Code.: 2901299090
• Mol file: 13151-29-6.mol

Synonyms:1-Decene,4-methyl;4-Methyl-dec-1-en;4-Methyl-1-decene;4-methyl-dec-1-ene;4-Methyl-1-decen;

Chemical Property of 4-Methyl-1-decene

Chemical Property:

• Melting Point: -67.3°C (estimate)
• Refractive Index: 1.4218 (estimate)
• Boiling Point: 187.71°C (estimate)
• PSA: 0.00000
• Density: 0.7709 (estimate)
• LogP: 4.16900

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-Methyl-1-decene

There total 23 articles about 4-Methyl-1-decene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

2-bromooctane (557-35-7,60251-57-2) → 4-methyl-1-decene (13151-29-6)

Guidance literature:

With (allyl)2Cu(CN)Li₂; In tetrahydrofuran; at -22 ℃; for 1.5h;

DOI:10.1021/jo00195a009

Reference yield: 82.0%

2-bromooctane (557-35-7,60251-57-2) + allylmagnesium bromide (1730-25-2) → 4-methyl-1-decene (13151-29-6)

Guidance literature:

With silver nitrate; In diethyl ether; at 20 ℃; for 3h; Inert atmosphere;

DOI:10.1021/ja504361y

Reference yield: 35.0%

oct-1-ene (111-66-0,25068-25-1) + diallylzinc (1802-55-7) → 4-methyl-1-decene (13151-29-6)

Guidance literature:

at 50 ℃; for 72h;

DOI:10.1016/S0022-328X(00)89045-2

upstream raw materials:

allyl sodium

(2R)-2-bromooctane

(R)-(-)-2-iodooctane

allyllithium

Downstream raw materials:

(S)-4-methyl-decane

4-methyldecane

2-(4-Methyl-decyl)-cyclohexanon

Refernces

• 1、 Sauer,Braig. "". . p. 4275. Retrieved 1969.
• 2、 Korte,W.D. et al.. "-". . p. 603 - 604. Retrieved 1970.
• 3、 Shen, Ruwei,Iwasaki, Takanori,Terao, Jun,Kambe, Nobuaki. "Copper-catalyzed coupling reaction of unactivated secondary alkyl iodides with alkyl Grignard reagents in the presence of 1,3-butadiene as an effective additive". supporting information; experimental part. p. 9313 - 9315. Retrieved 2012/09/21.
• 4、 Someya, Hidenori,Ohmiya, Hirohisa,Yorimitsu, Hideki,Oshima, Koichiro. "Silver-catalyzed benzylation and allylation reactions of tertiary and secondary alkyl halides with grignard reagents". scheme or table. p. 969 - 971. Retrieved 2009/04/10.