9-Methylacenaphtho[1,2-b]quinoxaline

Base Information

• Chemical Name: 9-Methylacenaphtho[1,2-b]quinoxaline
• CAS No.: 13362-59-9
• Molecular Formula: C₁₉H₁₂N₂
• Molecular Weight: 268.318
• European Community (EC) Number: 654-654-2
• NSC Number: 163365
• DSSTox Substance ID: DTXSID00928210
• Nikkaji Number: J2.847.340K
• Wikidata: Q82902963
• Mol file: 13362-59-9.mol

Synonyms:9-methylacenaphtho[1,2-b]quinoxaline;13362-59-9;9-METHYLACENAPHTHO(1,2-B)-QUINOXALINE;9-methylacenaphthyleno[1,2-b]quinoxaline;NSC163365;9-methyl-acenaphtho[1,2-b]quinoxaline;SCHEMBL3830394;DTXSID00928210;FEBHQCJWEFRRBQ-UHFFFAOYSA-N;C19H12N2;CCG-48687;STK533823;AKOS002345479;NSC-163365;FT-0723494;AO-022/40777499;SR-01000638208-1

Chemical Property of 9-Methylacenaphtho[1,2-b]quinoxaline

Chemical Property:

• Vapor Pressure: 1.21E-09mmHg at 25°C
• Melting Point: 210-211 °C(Solv: ethanol (64-17-5))
• Boiling Point: 500.1±30.0 °C(Predicted)
• Density: 1.349±0.06 g/cm3(Predicted)
• XLogP3: 4.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 268.100048391
• Heavy Atom Count: 21
• Complexity: 408

Purity/Quality:

9-Methylacenaphtho(1,2-B)quinoxaline ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC1=CC2=C(C=C1)N=C3C4=CC=CC5=C4C(=CC=C5)C3=N2

Technology Process of 9-Methylacenaphtho[1,2-b]quinoxaline

There total 4 articles about 9-Methylacenaphtho[1,2-b]quinoxaline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

4-methyl-1,2-diaminobenzene (496-72-0) + acenaphthene quinone (82-86-0) → 9-methyl-acenaphtho[1,2-b]quinoxaline (13362-59-9)

Guidance literature:

With sulfonated rice husk ash; at 20 ℃; for 0.166667h; Green chemistry;

DOI:10.1007/s11164-015-2075-5

Reference yield: 92.0%

1,2-dihydroacenaphthylene-1,2-diol (17976-92-0) + 4-methyl-1,2-diaminobenzene (496-72-0) → 9-methyl-acenaphtho[1,2-b]quinoxaline (13362-59-9)

Guidance literature:

With sodium hydroxide; In water; toluene; at 20 ℃; for 39h;

DOI:10.1002/cctc.201402782

Reference yield: 91.0%

2-hydroxyacenaphthylen-1-one (33928-29-9) + 4-methyl-1,2-diaminobenzene (496-72-0) → 9-methyl-acenaphtho[1,2-b]quinoxaline (13362-59-9)

Guidance literature:

With sodium hydroxide; In water; toluene; at 20 ℃; for 28h;

DOI:10.1002/cctc.201402782

upstream raw materials:

4-methyl-1,2-diaminobenzene

acenaphthene quinone

2-(2-oxo-2H-acenaphthylen-1-ylidene)malononitrile

2-hydroxyacenaphthylen-1-one