Molybdenum,tetracarbonylbis(triphenylphosphine)-

Base Information

• Chemical Name: Molybdenum,tetracarbonylbis(triphenylphosphine)-
• CAS No.: 15096-70-5
• Molecular Formula: C₄₀H₃₀MoO₄P₂
• Molecular Weight: 732.563
• NSC Number: 138881
• Mol file: 15096-70-5.mol

Synonyms:Molybdenum,tetracarbonylbis(triphenylphosphine)-;15096-70-5;NSC138881;NSC-138881;Molybdenum, tetracarbonylbis(triphenylphosphine)-;Molybdenum,tetracarbonylbis(triphenylphosphine)-(OC-6-12)-;16244-53-4

Chemical Property of Molybdenum,tetracarbonylbis(triphenylphosphine)-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 6
• Exact Mass: 736.082987
• Heavy Atom Count: 47
• Complexity: 657

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].C1=CC=C(C=C1)[PH+](C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)[PH+](C2=CC=CC=C2)C3=CC=CC=C3.[Mo]

Technology Process of Molybdenum,tetracarbonylbis(triphenylphosphine)-

There total 20 articles about Molybdenum,tetracarbonylbis(triphenylphosphine)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

(bicyclo[2.2.1]hepta-2,5-diene)tetracarbonylmolybdenum(0) (12146-37-1,124717-04-0) + triphenylphosphine (603-35-0) → cis-{molybdenum(0)(carbonyl)4(P(phenyl)3)2} (15096-70-5,16244-53-4,16742-93-1) + bicyclo[2.2.1]hepta-2,5-diene (121-46-0)

Guidance literature:

In tetrahydrofuran; reaction in a calorimeter under argon;

Reference yield: 90.0%

molybdenum hexacarbonyl (13939-06-5,199620-15-0) → Mo(CO)4(P(C6H5)3)2 (16742-93-1,15096-70-5,16244-53-4)

Guidance literature:

With triphenylphosphine; {Fe₂(SCH₃)2(CO)4(P(C₆H₅)3)2}; In cyclohexane; 80°C, N2, daylight, 3 h;

DOI:10.1021/om00127a036

Reference yield: 85.0%

triphenylphosphine (603-35-0) + molybdenum hexacarbonyl (13939-06-5,199620-15-0) → triphenylphosphinemolybdenumpentacarbonyl (14971-42-7) + trans-Mo(CO)4(PPh3)2 (15096-70-5,16244-53-4,16742-93-1)

Guidance literature:

In tetrahydrofuran; diethylene glycol dimethyl ether; other Radiation; heating of diglyme and thf soln. of Mo(CO)6 (1 equiv.) and PPh3 (1 equiv.) for 40 min in microwave oven; cooling in ice bath, pptn., filtration, washing with hexane, drying in air; removal of thf and hexane from the washing under reduced pressure, cooling in ice bath, pptn., filtration, washing with cold hexane, drying in air;

DOI:10.1016/j.jorganchem.2004.04.030

upstream raw materials:

molybdenum hexacarbonyl

cis-tetracarbonylbis(piperidine)molybdenum

triphenylphosphine

triphenylphosphinemolybdenumpentacarbonyl

Downstream raw materials:

triphenylphosphinemolybdenumpentacarbonyl

triphenylphosphine

trans-Mo(CO)4(PPh₃)2

MoBr₂(NO)2(P(C₆H₅)3)2