Benzoic acid (2S,3aS,4S,4aR,5S,6S,8S,8aS,10R)-5-acetoxymethyl-2,5,6-trihydroxy-3a-isopropenyl-1,8a-dimethyl-9-oxo-8,10-bis-(2,2,2-trichloro-ethoxycarbonyloxy)-2,3,3a,4,4a,5,6,7,8,8a,9,10-dodecahydro-benzo[f]azulen-4-yl ester

Base Information

Chemical Name:Benzoic acid (2S,3aS,4S,4aR,5S,6S,8S,8aS,10R)-5-acetoxymethyl-2,5,6-trihydroxy-3a-isopropenyl-1,8a-dimethyl-9-oxo-8,10-bis-(2,2,2-trichloro-ethoxycarbonyloxy)-2,3,3a,4,4a,5,6,7,8,8a,9,10-dodecahydro-benzo[f]azulen-4-yl ester
CAS No.:144654-48-8
Molecular Formula:C₃₅H₃₈Cl₆O₁₄
Molecular Weight:895.396
Hs Code.:

Benzoic acid (2S,3aS,4S,4aR,5S,6S,8S,8aS,10R)-5-acetoxymethyl-2,5,6-trihydroxy-3a-isopropenyl-1,8a-dimethyl-9-oxo-8,10-bis-(2,2,2-trichloro-ethoxycarbonyloxy)-2,3,3a,4,4a,5,6,7,8,8a,9,10-dodecahydro-benzo[f]azulen-4-yl ester

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Chemical Property of Benzoic acid (2S,3aS,4S,4aR,5S,6S,8S,8aS,10R)-5-acetoxymethyl-2,5,6-trihydroxy-3a-isopropenyl-1,8a-dimethyl-9-oxo-8,10-bis-(2,2,2-trichloro-ethoxycarbonyloxy)-2,3,3a,4,4a,5,6,7,8,8a,9,10-dodecahydro-benzo[f]azulen-4-yl ester

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Technology Process of Benzoic acid (2S,3aS,4S,4aR,5S,6S,8S,8aS,10R)-5-acetoxymethyl-2,5,6-trihydroxy-3a-isopropenyl-1,8a-dimethyl-9-oxo-8,10-bis-(2,2,2-trichloro-ethoxycarbonyloxy)-2,3,3a,4,4a,5,6,7,8,8a,9,10-dodecahydro-benzo[f]azulen-4-yl ester

There total 3 articles about Benzoic acid (2S,3aS,4S,4aR,5S,6S,8S,8aS,10R)-5-acetoxymethyl-2,5,6-trihydroxy-3a-isopropenyl-1,8a-dimethyl-9-oxo-8,10-bis-(2,2,2-trichloro-ethoxycarbonyloxy)-2,3,3a,4,4a,5,6,7,8,8a,9,10-dodecahydro-benzo[f]azulen-4-yl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 95603-44-4
7,10-di-(2,2,2-trichloroethyloxycarbonyl)-10-deacetylbaccatin III

: 144654-48-8
Benzoic acid (2S,3aS,4S,4aR,5S,6S,8S,8aS,10R)-5-acetoxymethyl-2,5,6-trihydroxy-3a-isopropenyl-1,8a-dimethyl-9-oxo-8,10-bis-(2,2,2-trichloro-ethoxycarbonyloxy)-2,3,3a,4,4a,5,6,7,8,8a,9,10-dodecahydro-benzo[f]azulen-4-yl ester

Guidance literature:: With zinc(II) chloride; In toluene; at 80 ℃; for 15h; other acid, other reaction conditions; rearrangement reactions;
DOI:10.1016/S0040-4020(01)91208-6

Reference yield: 12.0%

: 95603-44-4
7,10-di-(2,2,2-trichloroethyloxycarbonyl)-10-deacetylbaccatin III

: 144654-52-4
C₃₅H₄₀Cl₆O₁₅

: 144654-51-3
C₃₅H₄₀Cl₆O₁₅

: 144654-48-8
Benzoic acid (2S,3aS,4S,4aR,5S,6S,8S,8aS,10R)-5-acetoxymethyl-2,5,6-trihydroxy-3a-isopropenyl-1,8a-dimethyl-9-oxo-8,10-bis-(2,2,2-trichloro-ethoxycarbonyloxy)-2,3,3a,4,4a,5,6,7,8,8a,9,10-dodecahydro-benzo[f]azulen-4-yl ester

: 144654-50-2
C₃₅H₃₈Cl₆O₁₄

Guidance literature:: With trifluoroacetic acid; In toluene; for 8h; Further byproducts given; Ambient temperature;
DOI:10.1016/S0040-4020(01)91208-6

Reference yield: 12.0%

: 95603-44-4
7,10-di-(2,2,2-trichloroethyloxycarbonyl)-10-deacetylbaccatin III

: 144654-52-4
C₃₅H₄₀Cl₆O₁₅

: 144654-48-8
Benzoic acid (2S,3aS,4S,4aR,5S,6S,8S,8aS,10R)-5-acetoxymethyl-2,5,6-trihydroxy-3a-isopropenyl-1,8a-dimethyl-9-oxo-8,10-bis-(2,2,2-trichloro-ethoxycarbonyloxy)-2,3,3a,4,4a,5,6,7,8,8a,9,10-dodecahydro-benzo[f]azulen-4-yl ester

: 144654-50-2
C₃₅H₃₈Cl₆O₁₄

: 144654-49-9
C₃₅H₃₆Cl₆O₁₃

Guidance literature:: With trifluoroacetic acid; In toluene; for 8h; Further byproducts given; Ambient temperature;
DOI:10.1016/S0040-4020(01)91208-6