Pt₂Cl₂(CNC₆H₂(CH₃)(C₄H₉)2)4

Base Information

Chemical Name:Pt₂Cl₂(CNC₆H₂(CH₃)(C₄H₉)2)4
CAS No.:95891-19-3
Molecular Formula:C₆₄H₉₂Cl₂N₄Pt₂
Molecular Weight:1378.53
Hs Code.:

Pt<sub>2</sub>Cl<sub>2</sub>(CNC<sub>6</sub>H<sub>2</sub>(CH<sub>3</sub>)(C<sub>4</sub>H<sub>9</sub>)2)4

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Chemical Property of Pt₂Cl₂(CNC₆H₂(CH₃)(C₄H₉)2)4

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Technology Process of Pt₂Cl₂(CNC₆H₂(CH₃)(C₄H₉)2)4

There total 3 articles about Pt₂Cl₂(CNC₆H₂(CH₃)(C₄H₉)2)4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

: 95891-16-0,127253-25-2
cis-PtCl₂(CN-C₆H₂-2,4-t-Bu₂-6-Me)2

: Pt₃(CNC₆H₂(CH₃)(C₄H₉)2)6

: 95891-19-3
Pt₂Cl₂(CNC₆H₂(CH₃)(C₄H₉)2)4

Guidance literature:: In acetonitrile; Electrolysis; deaerated (bubbling with N2) soln. of Pt-complex in MeCN was electrolyzed at -1.70 V (Hg pool working electrode, Pt wire as a counter electrode, supporting electrolyte n-Bu4NClO4) until 2 F of charge per mole of initial complex was consumed; soln. was sepd. by decantation, solvent was removed under reduced pressure, residue extd. with benzene or CH2Cl2, hexane was added to concd. ext. to give a ppt. of the dimer and trimer complexes;

Reference yield: 20.0%

: 95891-16-0,127253-25-2
cis-PtCl₂(CN-C₆H₂-2,4-t-Bu₂-6-Me)2

: 95891-19-3
Pt₂Cl₂(CNC₆H₂(CH₃)(C₄H₉)2)4

: 3Pt*6CNC₆H₂{C(CH₃)3}2(CH₃)=Pt₃{CNC₆H₂(C(CH₃)3)2(CH₃)}6

Guidance literature:: In acetonitrile; Electrolysis; potentiostatic electrolysis of the Pt-complex in CH3CN contg. 0.1 M n-Bu4NClO4 using a mercury pool electrode at -1.70V (vs. SCE) and 2x96.5 kC/mol charge;; elem. anal.;; Kinetics;
DOI:10.1246/cl.1985.201

Reference yield:

: Pt₃(CNC₆H₂(CH₃)(C₄H₉)2)6

: 95891-16-0,127253-25-2
cis-PtCl₂(CN-C₆H₂-2,4-t-Bu₂-6-Me)2

: 95891-19-3
Pt₂Cl₂(CNC₆H₂(CH₃)(C₄H₉)2)4

Guidance literature:: In acetonitrile; byproducts: Cl(1-); electrochemical generation of Pt(0)-comp. (polarographic reduction step), rapid decompn.;
DOI:10.1016/0013-4686(88)80217-2