(3'aS,6'S,7'S,8'S,8'aR,12'aR,13'aS)-decahydro-8'a,14',14'-trimethyl-2'-phenylspiro<1,3-dithiolane-2,12'(9'H)-<4H-3a,6>methanobenzo<4,5>cyclodeca<1,2-d><1,3>dioxole>-7',8'-diol diacetate

Base Information

Chemical Name:(3'aS,6'S,7'S,8'S,8'aR,12'aR,13'aS)-decahydro-8'a,14',14'-trimethyl-2'-phenylspiro<1,3-dithiolane-2,12'(9'H)-<4H-3a,6>methanobenzo<4,5>cyclodeca<1,2-d><1,3>dioxole>-7',8'-diol diacetate
CAS No.:132802-52-9
Molecular Formula:C₃₁H₄₂O₆S₂
Molecular Weight:574.803
Hs Code.:

(3'aS,6'S,7'S,8'S,8'aR,12'aR,13'aS)-decahydro-8'a,14',14'-trimethyl-2'-phenylspiro<1,3-dithiolane-2,12'(9'H)-<4H-3a,6>methanobenzo<4,5>cyclodeca<1,2-d><1,3>dioxole>-7',8'-diol diacetate

Synonyms:

Suppliers and Price of (3'aS,6'S,7'S,8'S,8'aR,12'aR,13'aS)-decahydro-8'a,14',14'-trimethyl-2'-phenylspiro<1,3-dithiolane-2,12'(9'H)-<4H-3a,6>methanobenzo<4,5>cyclodeca<1,2-d><1,3>dioxole>-7',8'-diol diacetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (3'aS,6'S,7'S,8'S,8'aR,12'aR,13'aS)-decahydro-8'a,14',14'-trimethyl-2'-phenylspiro<1,3-dithiolane-2,12'(9'H)-<4H-3a,6>methanobenzo<4,5>cyclodeca<1,2-d><1,3>dioxole>-7',8'-diol diacetate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (3'aS,6'S,7'S,8'S,8'aR,12'aR,13'aS)-decahydro-8'a,14',14'-trimethyl-2'-phenylspiro<1,3-dithiolane-2,12'(9'H)-<4H-3a,6>methanobenzo<4,5>cyclodeca<1,2-d><1,3>dioxole>-7',8'-diol diacetate

There total 5 articles about (3'aS,6'S,7'S,8'S,8'aR,12'aR,13'aS)-decahydro-8'a,14',14'-trimethyl-2'-phenylspiro<1,3-dithiolane-2,12'(9'H)-<4H-3a,6>methanobenzo<4,5>cyclodeca<1,2-d><1,3>dioxole>-7',8'-diol diacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 124126-52-9,124509-65-5
C₂₀H₃₀OS₂

: 132802-52-9
(3'aS,6'S,7'S,8'S,8'aR,12'aR,13'aS)-decahydro-8'a,14',14'-trimethyl-2'-phenylspiro<1,3-dithiolane-2,12'(9'H)-<4H-3a,6>methanobenzo<4,5>cyclodeca<1,2-d><1,3>dioxole>-7',8'-diol diacetate

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) osmium tetroxide, pyridine, 2.) LiAlH₄ / 1.) over night, room temperature, 2.) tetrahydrofuran, overnight

2: 85 percent / p-toluenesulfonic acid, 4 Angstroem molecular sieves / benzene / 3 h / Ambient temperature

3: 75 percent / Burgess reagent / benzene / Heating

4: 1.) osmium tetroxide, pyridine, 2.) LiAlH₄ / 1.) room temperature, overnight, 2.) tetrahydrofuran, 24 h

5: 1 mg / pyridine, DMPA / Ambient temperature

With pyridine; osmium(VIII) oxide; lithium aluminium tetrahydride; Burgess Reagent; 4 A molecular sieve; 0,2,4-dichlorophenyl-0-methylisopropylamidothiophosphate; toluene-4-sulfonic acid; In benzene;
DOI:10.1021/jo00007a038

Reference yield:

: 124126-53-0,132881-70-0
(4'aR,5'S,7'R,10'S,11'S,12'aR)-decahydro-4'a,13',13'-trimethylspiro<1,3-dithiolane-2,1'(2'H)-<7,10>methanobenzocyclodecene>-5',10',11'(5'H)-triol

: 132802-52-9
(3'aS,6'S,7'S,8'S,8'aR,12'aR,13'aS)-decahydro-8'a,14',14'-trimethyl-2'-phenylspiro<1,3-dithiolane-2,12'(9'H)-<4H-3a,6>methanobenzo<4,5>cyclodeca<1,2-d><1,3>dioxole>-7',8'-diol diacetate

Guidance literature:: Multi-step reaction with 4 steps

1: 85 percent / p-toluenesulfonic acid, 4 Angstroem molecular sieves / benzene / 3 h / Ambient temperature

2: 75 percent / Burgess reagent / benzene / Heating

3: 1.) osmium tetroxide, pyridine, 2.) LiAlH₄ / 1.) room temperature, overnight, 2.) tetrahydrofuran, 24 h

4: 1 mg / pyridine, DMPA / Ambient temperature

With pyridine; osmium(VIII) oxide; lithium aluminium tetrahydride; Burgess Reagent; 4 A molecular sieve; 0,2,4-dichlorophenyl-0-methylisopropylamidothiophosphate; toluene-4-sulfonic acid; In benzene;
DOI:10.1021/jo00007a038

Reference yield:

: 132802-50-7
(3'aS,6'R,8'S,8'aR,12'aR,13'aS)-decahydro-8'a,14',14'-trimethyl-2'-phenylspiro<1,3-dithiolane-2,12'(9'H)-<14H-3a,6>methanobenzo<4,5>cyclodeca<1,2-d><1,3>dioxol>-8'-ol

: 132802-52-9
(3'aS,6'S,7'S,8'S,8'aR,12'aR,13'aS)-decahydro-8'a,14',14'-trimethyl-2'-phenylspiro<1,3-dithiolane-2,12'(9'H)-<4H-3a,6>methanobenzo<4,5>cyclodeca<1,2-d><1,3>dioxole>-7',8'-diol diacetate

Guidance literature:: Multi-step reaction with 3 steps

1: 75 percent / Burgess reagent / benzene / Heating

2: 1.) osmium tetroxide, pyridine, 2.) LiAlH₄ / 1.) room temperature, overnight, 2.) tetrahydrofuran, 24 h

3: 1 mg / pyridine, DMPA / Ambient temperature

With pyridine; osmium(VIII) oxide; lithium aluminium tetrahydride; Burgess Reagent; 0,2,4-dichlorophenyl-0-methylisopropylamidothiophosphate; In benzene;
DOI:10.1021/jo00007a038